%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Pd                 1.13497200    0.08023100    0.00031700
 P                  2.55187200   -1.70850800    0.00134600
 Br                -0.43099900    2.04783600   -0.00078800
 C                 -1.12256300    0.05545200   -0.00073800
 C                 -1.58336800   -0.45051300   -1.22511100
 C                 -1.58720300   -0.44611800    1.22406200
 C                 -2.45785900   -1.54139600   -1.21070000
 H                 -1.25645200   -0.01343300   -2.16156800
 C                 -2.46192000   -1.53680100    1.21088000
 H                 -1.26304800   -0.00578500    2.15996700
 C                 -2.89532900   -2.09078600    0.00038200
 H                 -2.79954800   -1.95673200   -2.15472000
 H                 -2.80662900   -1.94865400    2.15532500
 H                 -3.58162000   -2.93203300    0.00082400
 H                  2.71557000   -2.48091400    1.17322900
 H                  2.31268100   -2.78454200   -0.88217500
 H                  3.92667100   -1.55420400   -0.29072100

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD





