%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                 -0.42132300   -2.08634500    0.58755800
 Pd                -0.40152200    0.18831200   -0.01625700
 Br                 2.93253200   -0.70058400   -1.10862400
 C                  1.52527900    0.77224700    0.18045300
 C                  2.14181300    0.98453200    1.44168900
 C                  1.09663300    1.88744400   -0.59766800
 C                  2.25224100    2.27597700    1.93509200
 H                  2.48956900    0.13932000    2.02649600
 C                  1.25336200    3.19911400   -0.07210500
 H                  0.86273700    1.77231800   -1.65282500
 C                  1.81422300    3.39215300    1.17987800
 H                  2.67061500    2.42956700    2.92702000
 H                  0.97071800    4.05060900   -0.68653500
 H                  1.93700300    4.39499300    1.57837400
 F                  0.78373467   -2.55604576    1.57958481
 F                 -0.26323199   -3.10502915   -0.67505431
 F                 -1.73250011   -2.67669106    1.35515563

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD





