%nproc=8
%mem=18200MB
# b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Br                -0.12363500    1.33522300    2.16689500
 P                  2.48407800   -0.83371700   -0.35200100
 Pd                 0.10450300   -0.45359200    0.01394300
 P                 -1.88609200   -1.79174100   -0.22097600
 C                 -0.41276000    1.58579200   -0.06649100
 C                  0.61880800    2.33177400   -0.66714900
 C                 -1.75538600    1.83035400   -0.41265200
 C                  0.31300800    3.19048900   -1.72942000
 H                  1.63839100    2.23936800   -0.31399700
 C                 -2.04118600    2.69457600   -1.47342200
 H                 -2.55711800    1.34480200    0.13025600
 C                 -1.01187300    3.36939900   -2.14366400
 H                  1.11838100    3.73309400   -2.21737700
 H                 -3.07693800    2.84721100   -1.76521000
 H                 -1.24336100    4.04758600   -2.95947000
 C                  3.15191835   -0.44592032   -2.00003104
 C                  4.50681960   -0.64347856   -2.26777114
 C                  2.30923316    0.04867271   -2.99542420
 C                  5.01896660   -0.34584669   -3.53044388
 H                  5.17106515   -1.03269364   -1.48257610
 C                  2.82118453    0.34551481   -4.25883247
 H                  1.24129914    0.20427141   -2.78462811
 C                  4.17584335    0.14847696   -4.52643779
 H                  6.08702712   -0.50094583   -3.74136446
 H                  2.15644515    0.73507877   -5.04358447
 H                  4.57986858    0.38302214   -5.52195198
 C                  3.69529096   -0.00801360    0.72669130
 C                  3.55756990   -0.07982484    2.11317876
 C                  4.76128078    0.69648567    0.16732147
 C                  4.48529735    0.55331761    2.94002465
 H                  2.71662215   -0.63467048    2.55385437
 C                  5.68993146    1.32904930    0.99429248
 H                  4.87007761    0.75303595   -0.92542477
 C                  5.55204140    1.25769654    2.38044981
 H                  4.37645752    0.49728636    4.03286998
 H                  6.53054702    1.88409883    0.55297659
 H                  6.28342926    1.75677706    3.03258995
 C                  2.99530408   -2.57072880   -0.16805015
 C                  2.86004773   -3.21088986    1.06417181
 C                  3.52220988   -3.26200968   -1.25894389
 C                  3.25226193   -4.54183001    1.20555098
 H                  2.44532475   -2.66538980    1.92421618
 C                  3.91367531   -4.59365655   -1.11794273
 H                  3.62871716   -2.75766961   -2.23024524
 C                  3.77892161   -5.23358636    0.11407525
 H                  3.14626491   -5.04628971    2.17693224
 H                  4.32870236   -5.13857276   -1.97834560
 H                  4.08804550   -6.28299686    0.22577286
 C                 -2.81437904   -1.65728705   -1.78065716
 C                 -4.19017019   -1.42694535   -1.75590183
 C                 -2.15041493   -1.78440515   -3.00071486
 C                 -4.90186858   -1.32443163   -2.95097424
 H                 -4.71346110   -1.32754138   -0.79385855
 C                 -2.86202021   -1.68090351   -4.19625458
 H                 -1.06605054   -1.96577478   -3.02041133
 C                 -4.23756153   -1.45109034   -4.17157666
 H                 -5.98638796   -1.14349995   -2.93153319
 H                 -2.33817893   -1.78076344   -5.15807189
 H                 -4.79891128   -1.37016673   -5.11372005
 C                 -3.22401355   -1.63924113    1.00340536
 C                 -4.39530826   -2.38212539    0.85286267
 C                 -3.07839199   -0.77979605    2.09230235
 C                 -5.42097280   -2.26502067    1.79069021
 H                 -4.51011828   -3.05902848   -0.00612665
 C                 -4.10387380   -0.66328141    3.03103622
 H                 -2.15522293   -0.19434704    2.21120306
 C                 -5.27510873   -1.40559957    2.88033950
 H                 -6.34448445   -2.85006620    1.67175965
 H                 -3.98860966    0.01412394    3.88970402
 H                 -6.08392058   -1.31347645    3.61968588
 C                 -1.57366207   -3.58344111   -0.15316555
 C                 -1.94768114   -4.31451305    0.97471520
 C                 -0.96041806   -4.22573720   -1.22877498
 C                 -1.70786014   -5.68745022    1.02716658
 H                 -2.43043465   -3.80771088    1.82285576
 C                 -0.72134580   -5.59925840   -1.17687251
 H                 -0.66572926   -3.64972196   -2.11787226
 C                 -1.09481820   -6.33013739   -0.04909980
 H                 -2.00206948   -6.26364650    1.91639953
 H                 -0.23818524   -6.10548298   -2.02526321
 H                 -0.90588311   -7.41266806   -0.00753994

-F -P -Br -S -O 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
5 6 7 8 10 12 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
9 11 13 14 15 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD








