%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Pd                -0.39810100   -0.85387600   -0.00580300
 P                 -2.34721300    0.16266100   -0.00051900
 Br                 1.95524400   -1.63345200    0.00525700
 C                  1.37934000    0.50735700    0.00200200
 C                  1.53786100    1.16013800   -1.22427300
 C                  1.52631900    1.16607600    1.22666400
 C                  1.76659200    2.54052800   -1.21232600
 H                  1.47182900    0.61670800   -2.15962100
 C                  1.75534100    2.54644600    1.20977200
 H                  1.45160000    0.62726900    2.16404700
 C                  1.87122900    3.23596100   -0.00251100
 H                  1.86695000    3.06610200   -2.15765000
 H                  1.84668600    3.07689700    2.15329200
 H                  2.05784200    4.30532000   -0.00429200
 C                 -2.97112770    0.92962425    1.52751824
 C                 -3.00324041    0.19568000    2.71358992
 C                 -3.41707799    2.25116223    1.51289439
 C                 -3.48184153    0.78300766    3.88457623
 H                 -2.65230851   -0.84641740    2.72461756
 C                 -3.89493503    2.83912956    2.68437078
 H                 -3.39167202    2.82982615    0.57821176
 C                 -3.92751225    2.10527249    3.87008978
 H                 -3.50776923    0.20436874    4.81934961
 H                 -4.24609825    3.88125278    2.67263062
 H                 -4.30477455    2.56816502    4.79350734
 C                 -2.58964377    1.61881213   -1.06506173
 C                 -3.72686253    1.71459967   -1.86757631
 C                 -1.63862411    2.63907073   -1.07855665
 C                 -3.91260663    2.83011504   -2.68387670
 H                 -4.47606437    0.90971923   -1.85728704
 C                 -1.82475827    3.75545325   -1.89431030
 H                 -0.74234736    2.56382020   -0.44597908
 C                 -2.96144699    3.85106523   -2.69701456
 H                 -4.80864182    2.90539332   -3.31692537
 H                 -1.07495396    4.55991904   -1.90443538
 H                 -3.10814421    4.73054042   -3.34067568
 C                 -3.89706955   -0.67884327   -0.45020247
 C                 -3.86963909   -2.00200393   -0.89175072
 C                 -5.11228202   -0.00103839   -0.35331412
 C                 -5.05713242   -2.64691915   -1.23695459
 H                 -2.91134836   -2.53584897   -0.96875811
 C                 -6.30032831   -0.64632262   -0.69764560
 H                 -5.13410188    1.04176438   -0.00515425
 C                 -6.27293312   -1.96901275   -1.13954755
 H                 -5.03552629   -3.68964655   -1.58559373
 H                 -7.25836342   -0.11178379   -0.62076134
 H                 -7.20910611   -2.47773082   -1.41172833

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
4 5 6 7 9 11 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
8 10 12 13 14 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD




