%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                  1.16277200   -0.13279400   -0.14025300
 Pd                -1.13806800   -0.15320200   -0.72032400
 Br                -2.54714600    1.95837100    0.05410200
 C                 -3.15552000   -0.09635900   -0.25770200
 C                 -3.22183400   -0.92701800    0.88255200
 C                 -4.04483900   -0.26326500   -1.33029000
 C                 -4.12686100   -1.99457100    0.88656900
 H                 -2.59743900   -0.72391300    1.74565400
 C                 -4.92624900   -1.34739000   -1.31074000
 H                 -4.01290500    0.41240400   -2.17753900
 C                 -4.97574200   -2.20841800   -0.20490900
 H                 -4.17338900   -2.64906600    1.75273000
 H                 -5.58234500   -1.51377400   -2.16085200
 H                 -5.68089300   -3.03409800   -0.19170600
 C                  1.29357000   -0.45168800    1.67553100
 C                  2.06967900   -1.48559100    2.21836600
 C                  0.52543000    0.34728700    2.54022500
 C                  2.07518600   -1.71817500    3.59810900
 H                  2.67108100   -2.11442700    1.56967600
 C                  0.54137000    0.12072100    3.91659700
 H                 -0.08950400    1.14830600    2.13539000
 C                  1.31344800   -0.91777900    4.44956400
 H                  2.68002700   -2.52519400    4.00278300
 H                 -0.05206300    0.75213200    4.57244000
 H                  1.31970700   -1.09869300    5.52079300
 C                  2.32992700   -1.35466000   -0.89117500
 C                  3.70602900   -1.12347300   -1.04634000
 C                  1.79229400   -2.57248300   -1.34074000
 C                  4.52400000   -2.09166500   -1.63438400
 H                  4.14131200   -0.18499300   -0.71667400
 C                  2.61265100   -3.54488700   -1.91560000
 H                  0.72337700   -2.75195000   -1.24446100
 C                  3.98067100   -3.30414200   -2.06643300
 H                  5.58626300   -1.89666800   -1.75442700
 H                  2.18177500   -4.48279500   -2.25518700
 H                  4.61905500   -4.05459900   -2.52439400
 C                  2.00673800    1.49561800   -0.35310400
 C                  1.64854900    2.28038900   -1.46174300
 C                  2.97982000    1.98009000    0.53594900
 C                  2.26180700    3.51447400   -1.68695100
 H                  0.87932500    1.92442200   -2.14315500
 C                  3.58706400    3.21868000    0.31376600
 H                  3.25928100    1.39506700    1.40744100
 C                  3.23164300    3.98601600   -0.79846600
 H                  1.97408000    4.11082700   -2.54842300
 H                  4.33702200    3.58270900    1.01077000
 H                  3.70290800    4.95023300   -0.96765200

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
4 5 6 7 9 11 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
8 10 12 13 14 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD




