%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Br                -0.31698800   -2.62154700   -2.02325800
 P                  2.05192500    0.57512800   -0.01733200
 Pd                 0.01372300   -0.68968000   -0.18188300
 P                 -2.23585000    0.28958200    0.09953800
 C                  0.61525100   -2.74306900   -0.01135300
 C                  1.96712200   -3.13108800   -0.02067700
 C                 -0.26338700   -3.22974000    0.97316400
 C                  2.46115900   -3.87956100    1.04674100
 H                  2.61993200   -2.82270800   -0.82780500
 C                  0.25782500   -3.97033500    2.04465300
 H                 -1.32865200   -3.04723500    0.89774200
 C                  1.61567600   -4.29348800    2.08910100
 H                  3.51539300   -4.14323900    1.06298900
 H                 -0.41537000   -4.31787500    2.82392900
 H                  2.01088500   -4.88599200    2.90885300
 C                  2.65812700    0.82224700    1.71869900
 C                  3.39498200    1.94820800    2.12259400
 C                  2.35280500   -0.16349600    2.67266200
 C                  3.82132900    2.08119900    3.44773200
 H                  3.63770300    2.72633000    1.40581900
 C                  2.78781600   -0.03564800    3.99501900
 H                  1.76637900   -1.02988000    2.38030000
 C                  3.52229200    1.08834300    4.38643100
 H                  4.38753500    2.95976100    3.74452300
 H                  2.54416000   -0.80857200    4.71846500
 H                  3.85375400    1.19297700    5.41565700
 C                  3.52809500   -0.13187400   -0.88659100
 C                  3.38163200   -0.48622900   -2.24055200
 C                  4.75653300   -0.37948400   -0.25588200
 C                  4.44241200   -1.05278200   -2.94954100
 H                  2.43021400   -0.32707500   -2.74152100
 C                  5.81683400   -0.95929900   -0.96332400
 H                  4.89395300   -0.12221100    0.78909200
 C                  5.66536300   -1.29369800   -2.31118400
 H                  4.31103600   -1.31624800   -3.99523500
 H                  6.75998300   -1.14639900   -0.45732400
 H                  6.48831500   -1.74329200   -2.85934100
 C                  2.01783100    2.31168100   -0.67878300
 C                  3.10387400    2.90123200   -1.34793400
 C                  0.85274100    3.07418300   -0.49104900
 C                  3.02576000    4.21800900   -1.81378700
 H                  4.01551400    2.33603900   -1.50956900
 C                  0.77722800    4.39264000   -0.94628600
 H                 -0.00296900    2.63325100    0.00947800
 C                  1.86376800    4.96865100   -1.61271300
 H                  3.87532100    4.65476400   -2.33149800
 H                 -0.13338200    4.96368100   -0.78948600
 H                  1.80326500    5.99078300   -1.97546000
 C                 -2.61535300    1.20108600    1.66531600
 C                 -3.93142800    1.48566300    2.07430500
 C                 -1.55084400    1.60867300    2.48398100
 C                 -4.17198300    2.18023700    3.26183000
 H                 -4.77094600    1.15478500    1.46932600
 C                 -1.79074700    2.30635200    3.67294100
 H                 -0.53206500    1.36484500    2.19620400
 C                 -3.10107900    2.59625200    4.06211800
 H                 -5.19360800    2.39342600    3.56375000
 H                 -0.95480500    2.61355900    4.29472900
 H                 -3.28939200    3.13429600    4.98681100
 C                 -3.64541200   -0.91615700    0.04479400
 C                 -4.49812800   -1.02647400   -1.06394600
 C                 -3.82407700   -1.80138700    1.12385300
 C                 -5.50148900   -2.00238200   -1.09650700
 H                 -4.38964500   -0.34803700   -1.90418100
 C                 -4.83002000   -2.76868200    1.09422100
 H                 -3.18347200   -1.72848400    1.99899000
 C                 -5.67133800   -2.87589800   -0.01992200
 H                 -6.15227900   -2.07211800   -1.96377400
 H                 -4.95594100   -3.43914900    1.93985600
 H                 -6.45098600   -3.63168600   -0.04515400
 C                 -2.65052400    1.47549300   -1.26712100
 C                 -2.09545000    1.21037000   -2.53232600
 C                 -3.45902900    2.61304200   -1.11317100
 C                 -2.36100300    2.04670500   -3.61965200
 H                 -1.44586900    0.34900600   -2.66286900
 C                 -3.71460600    3.45734600   -2.19904900
 H                 -3.89051100    2.85348100   -0.14811700
 C                 -3.17142600    3.17462600   -3.45568400
 H                 -1.92589200    1.82224900   -4.58940100
 H                 -4.33883100    4.33562700   -2.05938600
 H                 -3.37129700    3.83135800   -4.29756700

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
5 6 7 8 10 12 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
9 11 13 14 15 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD








