%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                 -2.20379500   -0.01830600   -0.08155400
 Pd                 0.06110200    0.90880500   -0.00345700
 P                  1.60703700   -0.88918000    0.18398200
 C                 -2.52379000   -1.32998900   -1.33985000
 C                 -1.79880400   -1.25915300   -2.54253200
 C                 -3.42963000   -2.38542300   -1.15579900
 C                 -1.98812400   -2.21232900   -3.54560400
 H                 -1.07544600   -0.46119700   -2.68926400
 C                 -3.60785600   -3.34586800   -2.15523700
 H                 -3.99154200   -2.47067100   -0.23188800
 C                 -2.89202900   -3.26027500   -3.35173700
 H                 -1.42271900   -2.14111300   -4.47049400
 H                 -4.30770300   -4.16142100   -1.99569700
 H                 -3.03339100   -4.00853200   -4.12639100
 C                 -2.89658800   -0.63599200    1.51096600
 C                 -4.28050200   -0.77543600    1.72259000
 C                 -2.01635600   -0.95126000    2.55773800
 C                 -4.76659600   -1.23710900    2.94644700
 H                 -4.98177300   -0.51240800    0.93615200
 C                 -2.50503900   -1.41002200    3.78429400
 H                 -0.94717600   -0.83180500    2.41643300
 C                 -3.87956500   -1.55651200    3.97915600
 H                 -5.83765900   -1.34196100    3.09472900
 H                 -1.81073600   -1.64790500    4.58525300
 H                 -4.26029500   -1.91127600    4.93274800
 C                 -3.39840900    1.32255000   -0.53713500
 C                 -3.70602200    2.30702700    0.41918100
 C                 -3.94373600    1.43854700   -1.82481800
 C                 -4.55044100    3.37035400    0.09837700
 H                 -3.28955100    2.24268100    1.42077000
 C                 -4.78250300    2.51078700   -2.14693600
 H                 -3.72282600    0.69239700   -2.58125400
 C                 -5.09016700    3.47753700   -1.18797000
 H                 -4.78811900    4.11411900    0.85408600
 H                 -5.20067000    2.58080900   -3.14732000
 H                 -5.74865400    4.30492700   -1.43667200
 C                  3.06836600   -0.46140100    1.22675800
 C                  2.83379500    0.07906100    2.50395300
 C                  4.39325100   -0.63385400    0.79974000
 C                  3.89864100    0.41199000    3.34385500
 H                  1.81513600    0.24371000    2.84566600
 C                  5.45836000   -0.28568500    1.63591900
 H                  4.60217700   -1.03322300   -0.18673100
 C                  5.21545200    0.23220600    2.91007500
 H                  3.69776100    0.81615800    4.33220100
 H                  6.47839800   -0.42292200    1.28795900
 H                  6.04477800    0.49627700    3.55999900
 C                  2.28032200   -1.45663700   -1.43653200
 C                  2.98359900   -2.66921700   -1.55437000
 C                  2.06792200   -0.67986700   -2.58525600
 C                  3.47034000   -3.08689600   -2.79378900
 H                  3.14799500   -3.29254100   -0.68030900
 C                  2.55331300   -1.10185900   -3.82640500
 H                  1.52914000    0.25857100   -2.50657700
 C                  3.25495000   -2.30431300   -3.93240600
 H                  4.01363400   -4.02454400   -2.86994000
 H                  2.37901700   -0.49102000   -4.70790200
 H                  3.63006200   -2.63348100   -4.89738200
 C                  1.00698600   -2.48082600    0.92232500
 C                  1.40620300   -2.94157900    2.18612500
 C                  0.08656700   -3.24775900    0.18504900
 C                  0.89444300   -4.13752500    2.70062200
 H                  2.12332500   -2.37996500    2.77405400
 C                 -0.41802500   -4.44303400    0.69799100
 H                 -0.23426400   -2.91663900   -0.79739300
 C                 -0.01773000   -4.89111000    1.96087000
 H                  1.21970200   -4.47975400    3.67919900
 H                 -1.12342300   -5.02265900    0.10926300
 H                 -0.41071600   -5.82151300    2.36074300
 C                  1.10521200    2.62732800    0.14663900
 C                  0.03149200    3.24028300   -0.54780800
 C                  1.53217700    3.12654400    1.39718800
 C                 -0.64342900    4.33042200    0.05649700
 H                 -0.16665400    3.00916100   -1.59074400
 C                  0.83891200    4.18602000    1.97099100
 H                  2.37157800    2.67004700    1.90881000
 C                 -0.24624900    4.79612800    1.30225000
 H                 -1.44309700    4.82514900   -0.48784100
 H                  1.13262200    4.54008600    2.95626500
 H                 -0.75699300    5.63844200    1.75978200
 Br                 3.15761400    2.67789100   -1.33703400

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
70 71 72 73 75 77 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
74 76 78 79 80 0
P   1 1.00       0.000000000000   
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****
 
Pd 0
SDD
 





