%nproc=8
%mem=18200MB
# b3lyp/gen pseudo=(read) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                 -0.83100991   -0.15858948   -2.41284452
 Pd                -0.33800700    0.11395200   -0.06313000
 Br                 0.07584136   -2.41683097    0.73504964
 C                  1.54527700   -0.99360200    0.06291800
 C                  2.15978027   -0.26377850    1.09892141
 C                  2.29746242   -1.39300818   -1.06158435
 C                  3.47049729    0.20352351    0.92372641
 H                  1.62871111   -0.07798804    2.02579963
 C                  3.60341128   -0.93586046   -1.20559104
 H                  1.84820744   -2.03880011   -1.80826234
 C                  4.19528644   -0.12189396   -0.22308099
 H                  3.93027608    0.79500161    1.71148413
 H                  4.17053880   -1.22015362   -2.08870051
 H                  5.21948513    0.21900685   -0.34066090
 C                 -1.75121334    1.18658978   -3.22285591
 C                 -3.13945253    1.25378855   -3.10141585
 C                 -1.06861724    2.15039282   -3.96494377
 C                 -3.84492224    2.28420943   -3.72251730
 H                 -3.67738047    0.49335467   -2.51693691
 C                 -1.77405527    3.18175258   -4.58547908
 H                  0.02554820    2.09768198   -4.06061307
 C                 -3.16200930    3.24873014   -4.46450538
 H                 -4.93921071    2.33688559   -3.62736251
 H                 -1.23555005    3.94176177   -5.17017762
 H                 -3.71845508    4.06112020   -4.95408359
 C                 -1.90080979   -1.58094935   -2.79339756
 C                 -2.32354903   -1.80487096   -4.10397838
 C                 -2.29798442   -2.44722788   -1.77488790
 C                 -3.14382826   -2.89446527   -4.39577970
 H                 -2.01087888   -1.12129137   -4.90659792
 C                 -3.11770667   -3.53776312   -2.06677515
 H                 -1.96474657   -2.27099246   -0.74192001
 C                 -3.54077109   -3.76142357   -3.37693908
 H                 -3.47758888   -3.07066934   -5.42866521
 H                 -3.43036654   -4.22085192   -1.26358916
 H                 -4.18748647   -4.62049617   -3.60726455
 C                  0.50308103   -0.40740743   -3.62556501
 C                  0.54574861   -1.57663011   -4.38554475
 C                  1.48278521    0.57081386   -3.79530300
 C                  1.56830733   -1.76780216   -5.31454887
 H                 -0.22634550   -2.34798903   -4.25094200
 C                  2.50516688    0.38017314   -4.72525017
 H                  1.44920770    1.49248234   -3.19653029
 C                  2.54815635   -0.78895304   -5.48474534
 H                  1.60235872   -2.68964739   -5.91316260
 H                  3.27725202    1.15181260   -4.85915789
 H                  3.35427698   -0.93988163   -6.21733419

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
4 5 6 7 9 11 0  
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
8 10 12 13 14 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD




