%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Pd                -0.40152200    0.18831200   -0.01625700
 P                 -2.75346696   -0.27705507   -0.27990631
 Br                 2.93253200   -0.70058400   -1.10862400
 C                  1.52527900    0.77224700    0.18045300
 C                  2.14181300    0.98453200    1.44168900
 C                  1.09663300    1.88744400   -0.59766800
 C                  2.25224100    2.27597700    1.93509200
 H                  2.48956900    0.13932000    2.02649600
 C                  1.25336200    3.19911400   -0.07210500
 H                  0.86273700    1.77231800   -1.65282500
 C                  1.81422300    3.39215300    1.17987800
 H                  2.67061500    2.42956700    2.92702000
 H                  0.97071800    4.05060900   -0.68653500
 H                  1.93700300    4.39499300    1.57837400
 C                 -3.24086227   -1.64179241   -1.38096844
 C                 -4.14417506   -2.60779469   -0.93674212
 C                 -2.71144282   -1.72193458   -2.66892823
 C                 -4.51740975   -3.65404349   -1.78011691
 H                 -4.56078911   -2.54475779    0.07898465
 C                 -3.08544506   -2.76789089   -3.51302989
 H                 -1.99961605   -0.96056015   -3.01927184
 C                 -3.98817216   -3.73396130   -3.06881287
 H                 -5.22892392   -4.41584314   -1.42982362
 H                 -2.66817364   -2.83059375   -4.52862190
 H                 -4.28264732   -4.55894978   -3.73362467
 C                 -3.67781664   -0.64594536    1.24387111
 C                 -5.04687552   -0.90759870    1.18315261
 C                 -3.01756226   -0.66719127    2.47235021
 C                 -5.75557059   -1.18976033    2.35078177
 H                 -5.56726380   -0.89001526    0.21458219
 C                 -3.72613756   -0.95039206    3.64030922
 H                 -1.93849922   -0.46116585    2.52036594
 C                 -5.09496098   -1.21152569    3.57973977
 H                 -6.83480041   -1.39539065    2.30307772
 H                 -3.20521142   -0.96747861    4.60871938
 H                 -5.65394008   -1.43408235    4.50023270
 C                 -3.70970300    1.10966264   -0.96912807
 C                 -4.47715142    0.92421825   -2.11939096
 C                 -3.67541884    2.35777374   -0.34736330
 C                 -5.20958427    1.98687837   -2.64808492
 H                 -4.50336074   -0.05968858   -2.60978083
 C                 -4.40879821    3.42060260   -0.87552937
 H                 -3.07074350    2.50406129    0.55933219
 C                 -5.17570952    3.23540150   -2.02578352
 H                 -5.81402160    1.84094998   -3.55508929
 H                 -4.38190047    4.40446292   -0.38484658
 H                 -5.75333559    4.07310695   -2.44278958

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
4 5 6 7 9 11 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
8 10 12 13 14 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD






