%nproc=8
%mem=18200MB
# b3lyp/gen pseudo=(read) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                 -2.50980900   -1.76074100    0.00131800
 Pd                -1.12047900    0.05903300   -0.00116200
 Br                 0.37085900    2.06507400    0.00084200
 C                  1.08388100    0.04175000    0.00080500
 C                  1.57115300   -0.44172700    1.22412100
 C                  1.57090800   -0.44017000   -1.22321000
 C                  2.49992800   -1.48587300    1.20973000
 H                  1.22554000   -0.01690200    2.15945800
 C                  2.49960200   -1.48441200   -1.21039600
 H                  1.22526200   -0.01401700   -2.15792300
 C                  2.96339400   -2.01349400   -0.00072900
 H                  2.86535400   -1.88134800    2.15362200
 H                  2.86478300   -1.87868100   -2.15488800
 H                  3.69299900   -2.81758700   -0.00131800
 C                 -2.54075219   -2.87915739    1.43679259
 H                 -2.83399172   -2.33248466    2.30860651
 H                 -3.24060136   -3.66872061    1.25874467
 H                 -1.56585533   -3.29379715    1.58695909
 C                 -2.30229427   -3.05013240   -1.26628109
 H                 -1.34419424   -3.51243088   -1.15128353
 H                 -3.06974557   -3.78726144   -1.15421281
 H                 -2.37094265   -2.60875333   -2.23858347
 C                 -4.31473915   -1.59896341   -0.16736860
 H                 -4.76395393   -2.56971313   -0.13996280
 H                 -4.69651135   -1.00643793    0.63765534
 H                 -4.54489197   -1.12562820   -1.09897122

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







