%nproc=8
%mem=18200MB
# b3lyp/gen pseudo=(read) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                 -3.13720090    1.01645799    0.00654329
 Pd                -0.83316000    0.32264100    0.00528400
 Br                 0.04587000   -2.05754600   -0.63625400
 C                  1.23185300   -0.33143200    0.04288600
 C                  2.17498500    0.15582300   -0.88168100
 C                  1.51380000   -0.33697800    1.41908800
 C                  3.34541800    0.74211800   -0.40745600
 H                  1.97798900    0.08881300   -1.94636300
 C                  2.69270600    0.27162300    1.87428200
 H                  0.83665500   -0.81746400    2.11683800
 C                  3.60672700    0.81497400    0.97129200
 H                  4.06151400    1.14584200   -1.11875100
 H                  2.89999800    0.29034200    2.94104400
 H                  4.52769700    1.26568200    1.32840900
 H                 -3.70458268    1.49145402    1.13568309
 H                 -4.11735937    0.13545323   -0.28606565
 H                 -3.59730272    2.00202066   -0.79312698

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD






