%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=n,n-DiMethylFormamide) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Br                -0.12072500    1.32998800    2.16716100
 P                  2.48506000   -0.82782600   -0.35529900
 Pd                 0.10528300   -0.45311500    0.01450300
 P                 -1.88222500   -1.79513500   -0.22119500
 C                 -0.41693900    1.58422000   -0.06636200
 C                  0.61130500    2.33350600   -0.66842900
 C                 -1.76093300    1.82700700   -0.40816300
 C                  0.30078200    3.19438700   -1.72752500
 H                  1.63206700    2.24227500   -0.31838600
 C                 -2.05157800    2.69341700   -1.46577800
 H                 -2.56008500    1.33866200    0.13605500
 C                 -1.02560500    3.37191100   -2.13735200
 H                  1.10362700    3.73995000   -2.21638200
 H                 -3.08850000    2.84504500   -1.75397100
 H                 -1.26081200    4.05186600   -2.95062400
 H                 -2.57204680   -1.69565944   -1.37737426
 H                 -2.87422570   -1.68439809    0.68774501
 H                 -1.64894343   -3.12392367   -0.17220142
 H                  2.97881043   -0.53753757   -1.57777319
 H                  3.38254278   -0.21372038    0.44463784
 H                  2.86866116   -2.11516139   -0.22069682

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD





