%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=n,n-DiMethylFormamide) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Pd                 0.84004800   -0.26698300    0.04776200
 P                  0.88798560   -1.49130667   -2.00402714
 Br                -0.27516400    2.07797600   -0.68608200
 C                 -1.24113300    0.24640600    0.05320700
 C                 -2.16183800   -0.35812100   -0.82528200
 C                 -1.46360200    0.25511900    1.44172300
 C                 -3.23065600   -1.07094200   -0.28888200
 H                 -2.01709400   -0.29815400   -1.89860100
 C                 -2.54103200   -0.48508800    1.95888200
 H                 -0.82940700    0.83798900    2.10086700
 C                 -3.41997000   -1.14894300    1.10355400
 H                 -3.92020200   -1.57556500   -0.96041600
 H                 -2.69979600   -0.50567000    3.03369800
 H                 -4.26346200   -1.70089300    1.50691000
 F                  0.54411104   -0.79960650   -3.43936723
 F                  2.28596076   -2.18643646   -2.47238598
 F                 -0.03730046   -2.81639725   -2.21587770

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD





