%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=n,n-DiMethylFormamide) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Pd                 0.84011200   -0.26697700    0.04767300
 P                  3.16032417   -0.83934371    0.04146685
 Br                -0.27514800    2.07796800   -0.68610800
 C                 -1.24115100    0.24644400    0.05324000
 C                 -2.16184900   -0.35810700   -0.82523900
 C                 -1.46365100    0.25521200    1.44174800
 C                 -3.23068200   -1.07090600   -0.28883500
 H                 -2.01708800   -0.29818200   -1.89855800
 C                 -2.54109000   -0.48497200    1.95891100
 H                 -0.82943400    0.83805700    2.10089300
 C                 -3.42002300   -1.14885400    1.10359500
 H                 -3.92021300   -1.57555400   -0.96036700
 H                 -2.69986600   -0.50552000    3.03372600
 H                 -4.26352300   -1.70078500    1.50695900
 C                  3.66512203   -2.46517979    0.68507865
 C                  4.22042301   -3.41374321   -0.17418831
 C                  3.49696101   -2.76287756    2.03735305
 C                  4.60682454   -4.65994255    0.31866336
 H                  4.35215591   -3.17901581   -1.24039245
 C                  3.88433789   -4.00905254    2.53070582
 H                  3.05947791   -2.01531369    2.71476417
 C                  4.43907525   -4.95761022    1.67161224
 H                  5.04394710   -5.40788940   -0.35868139
 H                  3.75200923   -4.24334432    3.59704100
 H                  4.74386767   -5.94023947    2.05999054
 C                  4.09609154   -0.95555251   -1.51520746
 C                  5.46223797   -1.23733155   -1.48845078
 C                  3.44749797   -0.76302935   -2.73496537
 C                  6.17968641   -1.32588143   -2.68119904
 H                  5.97343960   -1.38830033   -0.52661757
 C                  4.16482099   -0.85254676   -3.92821480
 H                  2.37073025   -0.54111164   -2.75624524
 C                  5.53073782   -1.13378609   -3.90151935
 H                  7.25662723   -1.54735889   -2.66015847
 H                  3.65308423   -0.70110983   -4.88981065
 H                  6.09661656   -1.20371134   -4.84183209
 C                  4.40345251    0.12898622    0.95216389
 C                  4.90479445    1.31059062    0.40541098
 C                  4.85489293   -0.31008721    2.19673779
 C                  5.85785745    2.05253772    1.10283994
 H                  4.54925127    1.65607548   -0.57615462
 C                  5.80751630    0.43248490    2.89495357
 H                  4.45973224   -1.24126011    2.62789214
 C                  6.30913280    1.61356782    2.34818025
 H                  6.25352974    2.98357330    0.67166400
 H                  6.16296809    0.08626392    3.87641130
 H                  7.06055056    2.19876450    2.89791885

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
4 5 6 7 9 11 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
8 10 12 13 14 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD



