%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=n,n-DiMethylFormamide) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                 -2.58732400   -0.76868000    0.45806100
 Pd                -0.32385400   -0.00898700    0.03853600
 P                 -0.03838700    2.35351100   -0.17621700
 Br                 1.09690800   -1.49275000   -1.87888700
 C                  0.78979100    3.01320800   -1.70060500
 H                  0.84569000    4.10776700   -1.68046300
 H                  1.80238600    2.60865100   -1.78171200
 H                  0.22657900    2.69932500   -2.58421700
 C                  0.92785500    3.20559700    1.15736100
 H                  1.93027900    2.77345900    1.21685000
 H                  1.00870100    4.28201600    0.96714800
 H                  0.43190400    3.04856600    2.11979900
 C                 -1.59100400    3.36927200   -0.17330200
 H                 -1.36754500    4.43981200   -0.24940400
 H                 -2.22276600    3.07625400   -1.01666400
 H                 -2.14590300    3.18576900    0.75156600
 C                 -3.98021500    0.19126200   -0.30104100
 H                 -3.85043400    0.22375300   -1.38677800
 H                 -4.95012100   -0.26352300   -0.06953900
 H                 -3.96720300    1.21779700    0.07536500
 C                 -3.13232500   -0.85098800    2.22853800
 H                 -3.07891700    0.14603100    2.67529200
 H                 -4.15839100   -1.22680800    2.31201100
 H                 -2.46258100   -1.51120400    2.78722300
 C                 -2.99457800   -2.48321000   -0.12324700
 H                 -4.03868900   -2.73964700    0.09061900
 H                 -2.82177700   -2.55419800   -1.20101200
 H                 -2.33953300   -3.20397300    0.37465000
 C                  1.68387000   -0.68830100    0.08422100
 C                  1.47572700   -1.62063400    1.12407600
 C                  2.83855400    0.12517300    0.08112600
 C                  2.32104000   -1.58946900    2.24874300
 H                  0.70749200   -2.38114000    1.03878600
 C                  3.67285200    0.12048500    1.19311300
 H                  3.04763700    0.77110400   -0.76454600
 C                  3.41175600   -0.72348000    2.29139300
 H                  2.14038100   -2.28509200    3.06431600
 H                  4.53514400    0.78231800    1.21101800
 H                  4.07891100   -0.72334600    3.14816200

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD




