%nproc=8
%mem=22000MB
%chk=thf_dosmet240pf3new.chk
#p ub3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf)

title

0 3
15           0        0.417942    1.897433    0.000055
 9           0       -0.181928    2.727286    1.218948
 9           0       -0.220614    2.733984   -1.194159
 9           0        1.876802    2.546194   -0.021814
 6           0       -6.342641   -1.606021    0.002374
35           0       -2.375568   -0.252953   -0.000121
46           0        0.120268   -0.396869   -0.001143
15           0        2.274174   -1.232641    0.000517
 9           0        3.180574   -1.006964   -1.289221
 9           0        2.526112   -2.794495    0.193046
 9           0        3.297322   -0.696144    1.096253
 1           0       -6.139021   -2.499058   -0.575722
 1           0       -6.275373   -1.633136    1.083005
 1           0       -6.603376   -0.683002   -0.500774

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

--link1--
%nproc=8
%mem=22000MB
%chk=thf_dosmet240pf3new.chk
#p ub3lyp/gen guess=(read,mix) geom=checkpoint scrf=(pcm,solvent=thf) opt=(ts,calcfc,noeigentest) freq  pseudo=(read)                  

title

0 1

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD



