%nproc=24
%mem=122000MB
%chk=thfthf_dosmet240.chk
#p ub3lyp/gen scrf=(pcm,solvent=thf) pseudo=(read) 

title

0 3
 15           0        0.101552    2.104916   -0.002007
  6           0        4.191408   -2.525718    0.000865
 35           0        2.369857   -0.726466    0.000932
 46           0       -0.141260   -0.224379   -0.005962
 15           0       -2.371010   -1.040316   -0.000722
  1           0        4.613990   -2.357476   -0.983569
  1           0        4.773993   -2.194783    0.853630
  1           0        3.579554   -3.411071    0.132516
  6           0       -1.440226    3.122208   -0.090299
  1           0       -2.080953    2.895123    0.765961
  1           0       -1.201208    4.191648   -0.085562
  1           0       -1.987740    2.881647   -1.005688
  6           0        1.103360    2.820570   -1.383132
  1           0        1.169992    3.910809   -1.295029
  1           0        2.108200    2.391259   -1.358484
  1           0        0.642052    2.565874   -2.341523
  6           0        0.934813    2.812069    1.490904
  1           0        1.009149    3.902997    1.418381
  1           0        0.365031    2.550474    2.387001
  1           0        1.936970    2.384911    1.581085
  6           0       -3.777080    0.162321    0.001541
  1           0       -3.714406    0.800131    0.887390
  1           0       -3.720560    0.797887   -0.886304
  1           0       -4.738420   -0.363171    0.005785
  6           0       -2.824649   -2.127203   -1.432084
  1           0       -2.145671   -2.983764   -1.469787
  1           0       -3.855336   -2.488720   -1.342011
  1           0       -2.722705   -1.566360   -2.365619
  6           0       -2.813356   -2.118081    1.441129
  1           0       -3.845021   -2.479364    1.362116
  1           0       -2.134649   -2.974872    1.478567
  1           0       -2.703043   -1.551433    2.370198

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

--link1--
%nproc=24
%mem=122000MB
%chk=thfthf_dosmet240.chk
#p ub3lyp/gen guess=(read,mix) scrf=(pcm,solvent=thf) geom=checkpoint opt=(maxstep=3,maxcyc=300,ts,calcfc,noeigentest) freq pseudo=(read)                  

title

0 1

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD



