%nproc=24
%mem=122000MB
%chk=dmf_onemetBpph3.chk
#p ub3lyp/gen scrf=(pcm,solvent=n,n-DiMethylFormamide) pseudo=(read) 

title

0 3
 C                 -5.99379100    0.07512500   -0.00161900
 Br                -3.29707600   -0.02063400   -0.44416600
 Pd                -1.03581500   -0.02903500   -1.59441400
 H                 -6.17401900    1.04125800   -0.45691900
 H                 -6.27000300   -0.81592700   -0.55219000
 H                 -5.92591300    0.01612500    1.07787100
 P                  0.67663900    0.00250000   -0.08613800
 C                  0.81057900    1.54562300    0.91682000
 C                  2.31899700   -0.16011300   -0.91149100
 C                  0.63700600   -1.35719700    1.15792600
 C                  2.04102100    2.15974700    1.20046500
 C                 -0.37283800    2.12343900    1.41013800
 C                  2.54158000    0.58817700   -2.08217000
 C                  3.33383300   -1.00921600   -0.44274000
 C                  1.08937800   -1.19292300    2.47699000
 C                  0.13803300   -2.60848900    0.75739300
 C                  2.08716500    3.32715800    1.97022200
 H                  2.96517300    1.73369700    0.82341100
 C                 -0.32226900    3.28266000    2.18760400
 H                 -1.33233900    1.66870100    1.17891400
 C                  3.76009800    0.50245900   -2.75849600
 H                  1.75901400    1.23826200   -2.46631100
 C                  4.55076200   -1.10056000   -1.12728000
 H                  3.18136400   -1.60024400    0.45438200
 C                  1.04995300   -2.26426300    3.37543800
 H                  1.47110900   -0.23270300    2.80885600
 C                  0.10801900   -3.67993700    1.65303100
 H                 -0.23571100   -2.73785500   -0.25509800
 C                  0.90785500    3.88884500    2.46783600
 H                  3.04544200    3.79375000    2.18001500
 H                 -1.24327600    3.71759100    2.56519600
 C                  4.76784200   -0.34492300   -2.28298700
 H                  3.91911000    1.08914300   -3.65864000
 H                  5.32721000   -1.76230400   -0.75417600
 C                  0.56298600   -3.50911900    2.96529400
 H                  1.40013400   -2.12371600    4.39401900
 H                 -0.27929000   -4.64188900    1.32992600
 H                  0.94553200    4.79519600    3.06526800
 H                  5.71302900   -0.41850000   -2.81295800
 H                  0.53174000   -4.33921900    3.66510300

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

--link1--
%nproc=24
%mem=122000MB
%chk=dmf_onemetBpph3.chk
#p ub3lyp/gen guess=(read,mix) scrf=(pcm,solvent=n,n-DiMethylFormamide) geom=checkpoint opt=(maxcyc=300,maxstep=3,ts,calcfc,noeigentest) freq pseudo=(read)

title

0 1

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD



