%nproc=24
%mem=122000MB
%chk=dmf_onemetBph3.chk
#p ub3lyp/gen scrf=(pcm,solvent=n,n-DiMethylFormamide) pseudo=(read) 

title

0 3
 P                 -1.98423600    0.40249800   -0.00001600
 C                  4.63727900    0.68823200   -0.00068900
 Br                 1.96120400    0.27892200    0.00030600
 Pd                -0.21767000   -1.03508700   -0.00001900
 H                  4.86239200    0.18418200    0.93145700
 H                  4.86278100    0.17617800   -0.92836800
 H                  4.60908700    1.77139700   -0.00536200
 H                 -2.03746747    1.24007152    1.05740398
 H                 -2.03304444    1.24511715   -1.05363391
 H                 -3.21319864   -0.15619234   -0.00400778

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

--link1--
%nproc=24
%mem=122000MB
%chk=dmf_onemetBph3.chk
#p ub3lyp/gen guess=(read,mix) scrf=(pcm,solvent=n,n-DiMethylFormamide) geom=checkpoint opt=(maxstep=2,maxcyc=300,ts,calcfc,noeigentest) freq pseudo=(read)                  

title

0 1

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD



