%nproc=24
%mem=122000MB
%chk=dmf_dosmet240ph3.chk
#p ub3lyp/gen pseudo=(read) scrf=(pcm,solvent=n,n-DiMethylFormamide)

title

0 3
 15           0        1.323798    2.063751    0.001202
  1           0        0.889441    2.908021    1.048422
  1           0        0.945307    2.889455   -1.081980
  1           0        2.695573    2.406108    0.033988
  6           0       -4.330197   -1.014034    0.003023
 35           0       -1.840990    0.180806   -0.001322
 46           0        0.658205   -0.181550   -0.000011
 15           0        2.627191   -1.483925    0.000607
  1           0        2.947392   -2.275775   -1.127311
  1           0        2.827566   -2.480144    0.985519
  1           0        3.881356   -0.845913    0.133806
  1           0       -4.316948   -1.321653    1.041129
  1           0       -4.877114   -0.119886   -0.269778
  1           0       -4.119004   -1.750276   -0.762317

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

--link1--
%nproc=24
%mem=122000MB
%chk=dmf_dosmet240ph3.chk
#p ub3lyp/gen guess=(read,mix) geom=checkpoint scrf=(pcm,solvent=n,n-DiMethylFormamide) opt=(modredun) pseudo=(read)                  

title

0 1

5 6 F
6 7 F

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

--link1--
%nproc=24
%mem=122000MB
%chk=dmf_dosmet240ph3.chk
#p ub3lyp/gen guess=(read,mix) geom=checkpoint scrf=(pcm,solvent=n,n-DiMethylFormamide) opt=(modredun,ts,calcfc,noeigentest,maxstep=2) freq  pseudo=(read)                  

title

0 1

5 6 A
6 7 A

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD



