%nproc=24
%mem=122000MB
%chk=thf_dosmet240ph3.chk
#p ub3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf)

title

0 3
  15           0        1.308918    2.067097   -0.001844
   1           0        0.871820    2.918758    1.038580
   1           0        0.938815    2.889848   -1.090432
   1           0        2.681244    2.403338    0.036626
   6           0       -4.284508   -0.999323   -0.004747
  35           0       -1.852779    0.165270    0.001308
  46           0        0.659803   -0.178779    0.001759
  15           0        2.640261   -1.471115   -0.001283
   1           0        2.972526   -2.248081   -1.135883
   1           0        2.848832   -2.474666    0.974342
   1           0        3.885174   -0.818453    0.142139
   1           0       -4.404727   -1.085833    1.068345
   1           0       -4.807895   -0.202145   -0.519020
   1           0       -4.020074   -1.887206   -0.566000

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

--link1--
%nproc=24
%mem=122000MB
%chk=thf_dosmet240ph3.chk
#p ub3lyp/gen guess=(read,mix) geom=checkpoint scrf=(pcm,solvent=thf) opt=(modredun) pseudo=(read)                  

title

0 1

5 6 F
6 7 F

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

--link1--
%nproc=24
%mem=122000MB
%chk=thf_dosmet240ph3.chk
#p ub3lyp/gen guess=(read,mix) geom=checkpoint scrf=(pcm,solvent=thf) opt=(modredun,ts,calcfc,noeigentest,maxstep=2) freq  pseudo=(read)                  

title

0 1

5 6 A
6 7 A

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD



