%nproc=24
%mem=122000MB
%chk=thf_dostransph3.chk
#p ub3lyp/gen scrf=(pcm,solvent=thf) pseudo=(read) 

title

0 3
 P                 -1.23895800    2.35778100    0.00079000
 C                  4.61385300   -0.00044000    0.00434100
 Br                 1.53921100   -0.00024300   -0.00235800
 Pd                -1.10645400    0.00014100    0.00029800
 P                 -1.23995300   -2.35744900    0.00079100
 H                  4.67071600    0.93547900   -0.53659200
 H                  4.66652200    0.00017100    1.08558800
 H                  4.67060500   -0.93697500   -0.53553700
 H                 -0.62684400   -3.04786200    1.06746700
 H                 -0.63307200   -3.04825000   -1.06919500
 H                 -2.48340900   -3.02829600    0.00450700
 H                 -0.62588700    3.04791100    1.06767000
 H                 -0.63144900    3.04833400   -1.06899900
 H                 -2.48212900    3.02916100    0.00413200

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

--link1--
%nproc=24
%mem=122000MB
%chk=thf_dostransph3.chk
#p ub3lyp/gen guess=(read,mix) geom=checkpoint opt=(ts,calcall,noeigentest) freq scrf=(pcm,solvent=thf) pseudo=(read) 

title

0 1

-C -F -H -P -Br 0
6-31+G(d,p)
****
-Pd 0
SDD
****

-Pd 0
SDD

