%nproc=8
%mem=18200MB
#p nosymm  scrf=(pcm,solvent=thf) ub3lyp/gen pseudo=(read) opt freq

title

0 2
 P                 -1.29250000   -2.64384659    0.83273485
 Pd                -1.84966400   -0.61754700   -0.12268800
 P                 -2.40933800    1.41788100   -1.08241500
 Br                 0.60062500   -0.31342300   -0.49016500
 F                 -1.98053200    1.64842500   -2.59775900
 F                 -1.77861400    2.73640400   -0.45310800
 F                 -3.92187000    1.91713700   -1.19543300
 F                  0.23622350   -3.03881518    1.04566297
 F                 -1.81732976   -2.94191744    2.30617942
 F                 -1.78664651   -3.98753730    0.13620111

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD






