%nproc=8
%mem=18200MB
#p nosymm  scrf=(pcm,solvent=thf) ub3lyp/gen pseudo=(read) opt freq

title

0 2
 P                 -1.29250000   -2.64384659    0.83273485
 Pd                -1.84966400   -0.61754700   -0.12268800
 P                 -2.40933800    1.41788100   -1.08241500
 Br                 0.60062500   -0.31342300   -0.49016500
 H                 -2.04563076    1.61342519   -2.36770855
 H                 -1.87426645    2.53644340   -0.54854555
 H                 -3.68809127    1.83997140   -1.17796480
 H                  0.00285354   -2.97852056    1.01315806
 H                 -1.71149980   -3.78319723    0.24212560
 H                 -1.73747422   -2.89656443    2.08198728

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD






