%nproc=8
%mem=18200MB
#p ub3lyp/gen pseudo=(read) opt freq

title

0 2
 P                 -2.12216001   -1.77888128   -0.08331385
 Pd                 0.09493200   -1.10331500   -0.05579100
 P                  2.38369395   -1.41006359   -0.09014580
 C                  3.32659387   -0.01615064   -0.86903818
 C                  4.46294156    0.57736155   -0.30018869
 C                  2.83249007    0.49902728   -2.08071435
 C                  5.09890366    1.65027880   -0.93426478
 H                  4.85347369    0.20919454    0.64356175
 C                  3.47236050    1.56203174   -2.71759349
 H                  1.93450513    0.06793195   -2.51692660
 C                  4.60885913    2.14272802   -2.14493894
 H                  5.98220792    2.09413947   -0.48161526
 H                  3.07843667    1.94458998   -3.65545247
 H                  5.10574585    2.97328202   -2.63938015
 C                  2.96159547   -2.89298360   -1.03302090
 C                  2.16695672   -4.05038500   -0.97784300
 C                  4.13810815   -2.91451890   -1.79753507
 C                  2.54961453   -5.20708664   -1.65747267
 H                  1.23876876   -4.03091922   -0.41163693
 C                  4.51349650   -4.07034516   -2.48724683
 H                  4.75968076   -2.02617187   -1.86116570
 C                  3.72286302   -5.21876342   -2.41600018
 H                  1.92428023   -6.09448055   -1.60517444
 H                  5.42468982   -4.07104191   -3.08001627
 H                  4.01545937   -6.11623067   -2.95472506
 C                  3.19195397   -1.61462028    1.56377989
 C                  4.23168930   -2.51985353    1.82028237
 C                  2.70557575   -0.82737058    2.62277588
 C                  4.78387086   -2.62271435    3.10064777
 H                  4.60586581   -3.15549095    1.02383688
 C                  3.26607944   -0.92149274    3.89697593
 H                  1.87453629   -0.15021809    2.43993448
 C                  4.30864086   -1.82102080    4.13902118
 H                  5.58567247   -3.33342702    3.28372088
 H                  2.87986817   -0.30484551    4.70495099
 H                  4.73921806   -1.90324259    5.13345726
 C                 -2.38790710   -3.44868441   -0.83250156
 C                 -2.62312469   -3.59147732   -2.20977655
 C                 -2.20265985   -4.60755783   -0.05928072
 C                 -2.69052592   -4.85820963   -2.79310871
 H                 -2.75244057   -2.71040147   -2.83143605
 C                 -2.27264914   -5.87262278   -0.64404631
 H                 -2.00105372   -4.52301317    1.00479927
 C                 -2.51875028   -6.00307509   -2.01284256
 H                 -2.87790680   -4.94778919   -3.86006020
 H                 -2.13331204   -6.75707532   -0.02767609
 H                 -2.57328423   -6.98860804   -2.46748426
 C                 -3.28128136   -0.68003923   -1.02423372
 C                 -2.80717530    0.57673915   -1.42948489
 C                 -4.61185384   -1.02591643   -1.31413047
 C                 -3.64331723    1.47092025   -2.10545132
 H                 -1.77810233    0.84919396   -1.20786904
 C                 -5.44564816   -0.13569544   -1.99075735
 H                 -4.99967092   -1.99644869   -1.01937060
 C                 -4.96340851    1.11564253   -2.38655316
 H                 -3.25973439    2.44213382   -2.40683554
 H                 -6.47185675   -0.41918234   -2.21042573
 H                 -5.61426227    1.80769913   -2.91471529
 C                 -2.93964643   -1.90970786    1.57636583
 C                 -4.14796006   -2.58924582    1.80088067
 C                 -2.32569758   -1.25351636    2.65420316
 C                 -4.73013152   -2.60439002    3.06894041
 H                 -4.63195548   -3.12220215    0.98785871
 C                 -2.91023375   -1.26546152    3.92364103
 H                 -1.38261498   -0.73947788    2.48473173
 C                 -4.11451468   -1.93950362    4.13295615
 H                 -5.66385123   -3.13811203    3.22683496
 H                 -2.41902042   -0.75637769    4.74924817
 H                 -4.56835216   -1.95423121    5.12043036
 Br                -0.08666775    1.14250504    0.82722308

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD






