%nproc=8
%mem=18200MB
#p nosymm  scrf=(pcm,solvent=thf) ub3lyp/gen pseudo=(read) opt freq

title

0 2
 P                 -1.34493745   -2.65287701    0.84262928
 Pd                -1.84966400   -0.61754700   -0.12268800
 P                 -2.40933800    1.41788100   -1.08241500
 Br                 0.60062500   -0.31342300   -0.49016500
 C                 -1.68798227    2.92586883   -0.36267989
 H                 -0.70208042    3.07074228   -0.75243522
 H                 -2.29817464    3.76814588   -0.61394598
 H                 -1.63959819    2.82528221    0.70148237
 C                 -4.13328685    1.98692140   -1.21123029
 H                 -4.70483276    1.27097803   -1.76409589
 H                 -4.54786250    2.09367203   -0.23060226
 H                 -4.16069523    2.93065975   -1.71472478
 C                 -1.96932124   -2.97718960    2.52113046
 H                 -3.00094085   -3.25658173    2.47013008
 H                 -1.40603305   -3.77192870    2.96384500
 H                 -1.86807247   -2.09372553    3.11622702
 C                 -1.93345882   -4.17855560    0.04366280
 H                 -1.72204788   -4.13672372   -1.00440949
 H                 -1.43538476   -5.02183067    0.47460295
 H                 -2.98894254   -4.27407693    0.19107310
 C                  0.38895527   -3.13986783    1.10503349
 H                  0.42255696   -4.10566405    1.56439019
 H                  0.89598729   -3.17492095    0.16344450
 H                  0.86769764   -2.42532611    1.74153634
 C                 -1.91900676    1.68150354   -2.81518112
 H                 -2.53692806    2.43951563   -3.24933654
 H                 -0.89537825    1.99077314   -2.85308888
 H                 -2.03644242    0.76920861   -3.36183167

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD






