%nproc=20
%Mem=40000MB
%Chk=IE12_TS2a_P_S4S18_F_A_2
#p SCRF=(SMD,Solvent=Dichloromethane) M06/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm  
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 Au                -1.25388236    0.18159328    2.94087667
 P                  0.65876819    1.39924974    3.57958981
 C                  2.02445708    1.31680287    2.37700677
 H                  1.69053617    1.71656706    1.41202300
 H                  2.88366672    1.90273701    2.73069956
 H                  2.33307709    0.27362152    2.23517720
 C                  1.39207335    0.82329273    5.14414867
 H                  2.29838622    1.39687812    5.37991767
 H                  0.66599219    0.94917896    5.95654487
 H                  1.64546916   -0.24126884    5.06767505
 C                  0.37337245    3.17821164    3.84718119
 H                  1.30593998    3.67546420    4.14698623
 H                  0.00204452    3.63967444    2.92381835
 H                 -0.37701627    3.31918689    4.63451639
 C                 -3.03590455   -0.70922085    2.33272534
 H                 -3.67485755   -1.04323185    3.15491234
 C                 -3.73974500   -0.15689600    1.18055400
 C                 -5.12095100    0.51017800    1.45529300
 C                 -5.09058100   -0.77194500    0.73184100
 H                 -3.17604700    0.31608200    0.37197800
 C                 -5.31954500   -0.80469400   -0.76035700
 H                 -6.39096800   -0.70852400   -0.98573800
 H                 -4.79168600   -0.00071100   -1.28632300
 H                 -4.97753000   -1.75816800   -1.18568200
 C                 -5.47718900   -2.04637700    1.44666500
 H                 -5.66947500   -1.86419700    2.51411900
 H                 -6.42249300   -2.41150900    1.02079200
 C                 -4.40744100   -3.13958400    1.28817100
 H                 -4.84757000   -4.10228800    1.58544000
 H                 -4.14020600   -3.24086100    0.22721700
 C                 -3.17729361   -2.76597068    2.14647472
 H                 -3.30648361   -2.98929768    3.21016372
 C                 -1.86036349   -2.68227897    1.80662269
 C                 -1.36358075   -2.54661642    0.40359133
 H                 -0.89058726   -3.48822365    0.08624017
 H                 -2.14663851   -2.30238811   -0.32200424
 H                 -0.58480331   -1.77196846    0.34417992
 C                 -0.80051126   -2.94079077    2.83323351
 H                  0.04787930   -2.24842277    2.73198660
 H                 -1.18769742   -2.87279211    3.85785457
 H                 -0.39834381   -3.95618308    2.68935178
 H                 -5.42380400    0.44946300    2.50476400
 C                 -5.33558800    1.86341100    0.83581400
 H                 -5.02328700    1.87161900   -0.21633700
 H                 -6.41137700    2.09575700    0.83595400
 C                 -4.58582200    2.93985300    1.60191500
 H                 -4.89335600    2.95674500    2.66108500
 H                 -3.50291700    2.72089500    1.62752900
 C                 -4.10341700    5.43272800    1.82472300
 H                 -4.23354300    6.39435900    1.31883900
 H                 -4.54437400    5.48382900    2.83010400
 H                 -3.03220600    5.22868600    1.96254600
 C                 -4.75186800    4.32951900    1.03801800
 O                 -5.37073500    4.53813500    0.01080100

15 31 F
15 33 F

C H P O 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD

--link1--
%nproc=20
%Mem=40000MB
%Chk=IE12_TS2a_P_S4S18_F_A_2
#p geom=checkpoint guess=read SCRF=(SMD,Solvent=Dichloromethane) M06/genecp opt=(ts,noeigentest,calcfc,modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm  
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

15 31 A
15 33 A

C H P O 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD



