%nprocshared=20
%mem=2GB
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.89169300    0.27294700   -0.07483700
 O                  2.39524700    0.64155500    1.29659400
 O                 -0.55667800   -0.25956200   -1.46362700
 O                  2.30934800    0.07805600   -1.57265500
 C                 -0.72640300   -0.79104600    2.06970900
 C                 -1.76414700   -0.72715400    3.21226200
 F                 -2.22883600    0.51747200    3.40353000
 F                 -2.80822400   -1.52821800    2.92921800
 F                 -1.21000000   -1.15156300    4.36143800
 O                 -0.46806700    0.29802100    1.49340500
 O                 -0.26060600   -1.94283300    1.85939200
 Rh                 1.19275300   -2.14360500    0.37927500
 O                  2.65856300   -1.57976100    1.75111400
 O                  2.61852700   -2.13999900   -1.13859600
 O                 -0.29499900   -2.48620200   -1.04382900
 C                  2.91423800   -0.35424300    1.87567200
 C                 -0.78803800   -1.48748700   -1.63136300
 C                  4.03607100    0.02403500    2.86745100
 F                  5.04678500    0.61362100    2.20035400
 F                  4.51996000   -1.04496600    3.51008700
 F                  3.57164100    0.89636900    3.77998600
 C                 -1.78707300   -1.84104700   -2.75563900
 F                 -2.69568500   -2.72943900   -2.32461900
 F                 -1.11769700   -2.38831000   -3.78760900
 F                 -2.43841900   -0.75577900   -3.21114900
 C                  2.83618200   -1.05802500   -1.74106800
 C                  3.90656600   -1.08063000   -2.85358400
 F                  4.41817700   -2.30307000   -3.03487500
 F                  3.36914100   -0.66568500   -4.01550900
 F                  4.90993800   -0.24173000   -2.53315200
 C                 -1.21316500    2.82068100   -0.79795200
 C                 -2.12689900    2.18870800    0.08020600
 H                 -1.23655100    2.49216900   -1.83438700
 H                 -2.15800000    2.49592500    1.11880600
 C                 -1.44486400    4.19893400   -0.55626600
 C                 -1.83414700    5.12111100   -1.67364000
 C                 -1.21268700    4.85828700    0.77275800
 C                 -0.80714600    6.27547700   -1.82245200
 H                 -2.80904900    5.56748400   -1.42923600
 H                 -1.94484000    4.57681200   -2.61582800
 C                 -0.15190700    5.97879300    0.60378200
 H                 -2.14214100    5.32407800    1.12852800
 H                 -0.87508400    4.14186000    1.52483100
 C                 -0.56356800    6.97926500   -0.48267600
 H                 -1.17851700    6.98054500   -2.57454900
 H                  0.13679100    5.86703400   -2.20298700
 H                 -0.02108400    6.48252600    1.56782200
 H                  0.81050700    5.52114100    0.34458200
 H                  0.20952600    7.74777100   -0.59861700
 H                 -1.48205000    7.49485800   -0.16992300
 O                  0.56542500    2.34491300   -0.41118500
 C                  1.43709400    2.94481000   -1.34984000
 H                  1.38708700    2.46639800   -2.33986000
 H                  1.17541300    4.00530500   -1.46974800
 H                  2.47339400    2.89897400   -0.99204800
 C                 -3.03014200    1.17037600   -0.33479600
 H                 -2.96877500    0.84189400   -1.36703500
 C                 -3.88838300    0.57282200    0.54072200
 H                 -3.87926800    0.92621200    1.57008700
 C                 -4.79019700   -0.53737100    0.27373000
 C                 -5.47049500   -1.12818700    1.36058800
 C                 -5.00856900   -1.06745700   -1.01704700
 C                 -6.32850700   -2.20827700    1.16888100
 H                 -5.30563900   -0.73883400    2.36101300
 C                 -5.86496400   -2.14750800   -1.20435500
 H                 -4.50614500   -0.63791100   -1.87558100
 C                 -6.52905200   -2.72385300   -0.11486500
 H                 -6.83837200   -2.65035300    2.02009100
 H                 -6.01510100   -2.54467000   -2.20424300
 H                 -7.19607300   -3.56747000   -0.26696700

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





