%nprocshared=12
%mem=2GB
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 C                 -0.76290300    1.91573100   -2.49085300
 C                 -0.62564900   -0.27222300   -2.40793200
 H                  0.19430200    2.29658000   -2.15691300
 C                 -0.72159800    0.87685400   -3.50316500
 C                 -1.96417100   -0.87928000   -2.19742200
 H                 -2.31532400   -1.47256900   -3.04649600
 C                 -2.77740200   -0.69304000   -1.14101400
 H                 -2.42122700   -0.07371900   -0.32613400
 C                 -4.13523500   -1.21793300   -0.95642000
 C                 -4.85312300   -0.80434900    0.18290300
 C                 -4.76687100   -2.09895800   -1.85666500
 C                 -6.15545000   -1.24777900    0.41363900
 H                 -4.37687100   -0.12731000    0.88766800
 C                 -6.06629200   -2.54286800   -1.62412600
 H                 -4.23762700   -2.44247000   -2.74056500
 C                 -6.76877900   -2.11888800   -0.48975500
 H                 -6.69025500   -0.91431200    1.29873700
 H                 -6.53508800   -3.22395500   -2.32920700
 H                 -7.78248800   -2.46719200   -0.31324300
 Rh                 0.61559900   -0.12125700   -0.51197800
 O                  2.12876000   -1.13788100   -1.51358600
 O                 -0.74846500    0.88965900    0.68191300
 O                 -0.21857100   -1.94003700    0.02781500
 C                  2.42568900    2.10116700    0.04059200
 C                  2.92855800    3.53189100   -0.24470200
 F                  3.50265900    3.59604300   -1.45872200
 F                  1.87346700    4.37724700   -0.23929000
 F                  3.80927900    3.95280900    0.66782500
 O                  1.64510600    1.66504900   -0.85342300
 O                  2.80962300    1.55824400    1.10303400
 Rh                 2.02637700   -0.32501700    1.57394900
 O                  3.44779600   -1.24492100    0.34928900
 O                  1.09072700   -2.16468000    1.88501900
 O                  0.45929500    0.61192200    2.59742000
 C                  3.16963600   -1.43653500   -0.86077000
 C                 -0.52928100    0.99045500    1.92116900
 C                  4.24143000   -2.15106500   -1.71347500
 F                  4.56882800   -1.38941300   -2.77451800
 F                  3.75361900   -3.31913500   -2.17381700
 F                  5.35470500   -2.40373000   -1.01567600
 C                 -1.62984800    1.74690400    2.69832800
 F                 -1.67447900    1.37034200    3.98221000
 F                 -2.84222600    1.54596700    2.15361800
 F                 -1.36773500    3.07134600    2.65515900
 C                  0.20680700   -2.51989700    1.06527000
 C                 -0.51139900   -3.85768200    1.34897800
 F                  0.03292500   -4.51246100    2.38194500
 F                 -1.80762900   -3.62071600    1.63093200
 F                 -0.45879300   -4.65376200    0.26554400
 H                  0.11476200   -0.96870800   -2.80586200
 H                  0.19193600    0.90982500   -4.09640200
 H                 -1.60082500    0.77178300   -4.14063700
 C                 -1.90988500    2.45777800   -1.85042600
 C                 -1.70658800    3.32549500   -0.74399900
 C                 -3.23555700    2.14700900   -2.25003000
 C                 -2.78910200    3.85390900   -0.05969500
 H                 -0.69159800    3.55459300   -0.43522600
 C                 -4.31336500    2.67847600   -1.55495800
 H                 -3.40966500    1.49972000   -3.10011900
 C                 -4.09108000    3.52287600   -0.45990900
 H                 -2.63031900    4.49874800    0.79728100
 H                 -5.32678200    2.43452500   -1.85623800
 H                 -4.93882700    3.92881600    0.08454700

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





