%nprocshared=20
%mem=2GB
#p opt=(ts,noeigentest,calcfc) freq=noraman b3lyp/genecp scrf=(solvent=dichloroethane,smd) empiricaldispersion=gd3 integral=grid=ultrafine

Title Card Required

0 1
 C                 -0.84089500    1.95840100   -2.40460800
 C                 -0.61401300   -0.23490900   -2.37371300
 H                  0.08609300    2.36255100   -2.01559000
 C                 -0.71783000    0.94904300   -3.43483000
 C                 -1.94526700   -0.86650000   -2.18315800
 H                 -2.28652200   -1.44864400   -3.04372200
 C                 -2.76111900   -0.71944300   -1.12168800
 H                 -2.41720200   -0.11037800   -0.29347600
 C                 -4.10781400   -1.27494200   -0.94606500
 C                 -4.84587200   -0.86965000    0.18343600
 C                 -4.70983800   -2.17764100   -1.84500100
 C                 -6.14062000   -1.33939100    0.40417300
 H                 -4.39118000   -0.17792500    0.88832500
 C                 -6.00171600   -2.64796500   -1.62227900
 H                 -4.16246100   -2.51906300   -2.71862800
 C                 -6.72538800   -2.23030700   -0.49894000
 H                 -6.69152700   -1.01158800    1.28150600
 H                 -6.44769200   -3.34568800   -2.32589600
 H                 -7.73287900   -2.59975600   -0.32996700
 Rh                 0.62826200   -0.12366700   -0.51055500
 O                  2.14428900   -1.12543800   -1.52218400
 O                 -0.73497200    0.88344500    0.68576900
 O                 -0.18445100   -1.94818900    0.04392400
 C                  2.39143600    2.13144200    0.02926300
 C                  2.83748400    3.58156100   -0.25172100
 F                  3.42034400    3.67097800   -1.45991900
 F                  1.74582400    4.37992700   -0.25721000
 F                  3.69056200    4.03983800    0.66914600
 O                  1.63696900    1.66669900   -0.87367600
 O                  2.78536200    1.60337700    1.09532500
 Rh                 2.05998500   -0.30890100    1.56518900
 O                  3.49144100   -1.19243600    0.32345600
 O                  1.16549700   -2.16956800    1.87401200
 O                  0.47579800    0.59335000    2.59766100
 C                  3.20076000   -1.39581500   -0.88195300
 C                 -0.51145900    0.97912400    1.92538600
 C                  4.28747000   -2.06191000   -1.75432500
 F                  4.69787000   -1.19611000   -2.70263200
 F                  3.78650800   -3.14844600   -2.37047600
 F                  5.35262500   -2.43699800   -1.03657000
 C                 -1.60837800    1.74218200    2.70048300
 F                 -1.59820200    1.44209200    4.00433600
 F                 -2.83102100    1.47180400    2.21014600
 F                 -1.39156400    3.07004000    2.57102100
 C                  0.26888100   -2.52872100    1.06947500
 C                 -0.42753100   -3.87695000    1.35820100
 F                  0.12067200   -4.51481100    2.39970500
 F                 -1.72976200   -3.66232000    1.62917200
 F                 -0.35279100   -4.68006900    0.28070500
 H                  0.11484400   -0.91650300   -2.81948700
 H                  0.21739600    1.03137200   -3.98814200
 H                 -1.56642300    0.82346500   -4.10916500
 C                 -2.03110700    2.43843500   -1.80042100
 C                 -1.90766600    3.28128100   -0.66275600
 C                 -3.32645000    2.08728900   -2.26379800
 C                 -3.03758000    3.74396000   -0.00864400
 H                 -0.91578400    3.54174700   -0.30705300
 C                 -4.45197400    2.55485600   -1.60016900
 H                 -3.43790800    1.46037400   -3.13938600
 C                 -4.30763300    3.37385500   -0.47285000
 H                 -2.93993100    4.36815600    0.87228900
 H                 -5.44188900    2.28117300   -1.94980900
 H                 -5.19236300    3.72930600    0.04752600

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LanL2DZ
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-P -C -H -O -Cl -F
6-31G(d,p)
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-Rh
LanL2DZ







