%nprocshared=20
%mem=8GB
%chk=CGMM_0034_TS10less.chk
#p opt=(maxstep=3) freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.72069100   -0.36069200    0.06008900
 O                  1.03917900   -1.62797400    1.65972300
 O                  0.57910600    0.93636900   -1.55927400
 O                  0.62130700    1.25961100    1.35700400
 C                  2.18377300   -2.20803100   -1.60631900
 C                  2.28664200   -3.45581400   -2.50977000
 F                  1.40077800   -3.37779500   -3.51798400
 F                  3.51070500   -3.59954000   -3.02969400
 F                  2.00030900   -4.55373000   -1.78251200
 O                  1.00341200   -1.94592000   -1.24041100
 O                  3.26146600   -1.62470100   -1.32294700
 Rh                 3.17674600    0.00227200   -0.02434900
 O                  3.29788800   -1.31286200    1.59174600
 O                  2.87590700    1.60366500    1.27630300
 O                  2.83182200    1.27617100   -1.64136200
 C                  2.23130200   -1.80752700    2.03738900
 C                  1.64237200    1.44268300   -2.01416600
 C                  2.35910500   -2.78226200    3.22846300
 F                  1.77301000   -3.95538400    2.92748700
 F                  1.73712100   -2.26705400    4.30563400
 F                  3.63681500   -3.01615400    3.54782700
 C                  1.43598100    2.46065500   -3.15729900
 F                  2.50615600    2.52820200   -3.95785600
 F                  1.22658100    3.68190300   -2.62291000
 F                  0.36458200    2.14313700   -3.90380900
 C                  1.69746100    1.86121600    1.63463700
 C                  1.53449300    3.14287300    2.48246400
 F                  2.61273500    3.36694100    3.24400100
 F                  1.38091200    4.19545200    1.64842300
 F                  0.45580600    3.08115800    3.27691400
 C                 -2.45838700    0.41884700   -1.14458600
 C                 -3.70348100   -0.20818800   -1.36987900
 H                 -1.74825500    0.32155700   -1.95690000
 H                 -3.81745200   -0.61950100   -2.37762100
 C                 -2.57700500    1.70548800   -0.58915100
 C                 -2.01355100    2.86216300   -1.35115400
 C                 -3.26248200    2.03496800    0.69776400
 C                 -1.10100900    3.73776000   -0.46469900
 H                 -2.86495800    3.47963600   -1.67378000
 H                 -1.48669400    2.52583700   -2.24498800
 C                 -2.34538600    2.92960900    1.57307900
 H                 -4.19468500    2.58106100    0.48746000
 H                 -3.50595000    1.13698000    1.26267000
 C                 -1.82760800    4.15513900    0.81482200
 H                 -0.77765200    4.60757200   -1.04453600
 H                 -0.20504600    3.16412600   -0.21148100
 H                 -2.91264800    3.22717200    2.46175200
 H                 -1.49688600    2.32865900    1.91277100
 H                 -1.14954300    4.72642700    1.45963600
 H                 -2.66769700    4.81652800    0.56187200
 O                 -1.34811700   -0.66510900    0.19314900
 C                 -1.75572200   -2.00842400    0.11578500
 H                 -2.83552200   -2.08356800    0.32005100
 H                 -1.56896100   -2.46298300   -0.86901900
 H                 -1.24247800   -2.61724300    0.87661900
 C                 -4.84732600   -0.33028400   -0.53741100
 H                 -4.76930900   -0.09485600    0.51766600
 C                 -6.02880800   -0.79437100   -1.03856900
 H                 -6.07689600   -1.00580400   -2.10658400
 C                 -7.25056800   -1.04813300   -0.29697700
 C                 -8.39774000   -1.46138600   -1.00982200
 C                 -7.35321300   -0.90666100    1.10564900
 C                 -9.59809600   -1.71377600   -0.35361000
 H                 -8.33378400   -1.57759000   -2.08889400
 C                 -8.55254000   -1.16353800    1.75773900
 H                 -6.48826600   -0.59823700    1.68766100
 C                 -9.68150700   -1.56673600    1.03344200
 H                -10.47019000   -2.02685500   -0.92165700
 H                 -8.61234000   -1.05046600    2.83656300
 H                -10.61702200   -1.76538200    1.54834200

-Rh
LanL2DZ
****
-P -C -H -O -Cl -F
6-31G(d,p)
****

-Rh
LanL2DZ





