%nprocshared=20
%mem=2GB
#p opt=(maxstep=3) freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                -1.28501100   -1.76382000    1.39628600
 O                 -2.06473800   -2.97114000   -0.11211300
 O                 -0.44612600   -0.41903600    2.75765000
 O                  0.62771400   -2.52111600    1.06161200
 C                 -3.39641000    0.14821400    0.81106400
 C                 -4.80074200    0.77810200    0.93676300
 F                 -5.43689800    0.36527700    2.03902900
 F                 -4.71308900    2.11878500    0.97097300
 F                 -5.53973100    0.43386400   -0.13659400
 O                 -3.14332500   -0.82114700    1.57146900
 O                 -2.67874100    0.68193500   -0.08035300
 Rh                -0.79601400   -0.11316100   -0.38950300
 O                 -1.59376300   -1.45200500   -1.74734500
 O                  1.06126300   -1.00891600   -0.58945700
 O                 -0.05972300    1.10680600    1.11060100
 C                 -2.04692600   -2.53893800   -1.29380400
 C                 -0.02418500    0.67027100    2.29415700
 C                 -2.69323500   -3.43832400   -2.36988800
 F                 -1.84326800   -3.62396900   -3.39468500
 F                 -3.80022200   -2.83614200   -2.84710500
 F                 -3.03922100   -4.63468000   -1.88184900
 C                  0.65760200    1.64889500    3.27384800
 F                 -0.00182100    2.82239700    3.27851200
 F                  1.92222200    1.88695200    2.86267000
 F                  0.69993200    1.17458600    4.52136000
 C                  1.33968400   -1.96482100    0.18342800
 C                  2.78577900   -2.49882800    0.08390500
 F                  3.51567900   -1.95605100    1.08084700
 F                  2.81674200   -3.83345700    0.22105300
 F                  3.35746500   -2.17742600   -1.08322400
 C                  1.11470200    2.43917000   -1.84951100
 C                  2.03143400    2.03786300   -0.85377200
 H                  1.81156200    2.26238300    0.18167700
 C                  0.75902500    3.76471700   -1.51638000
 C                  0.15766800    4.18449100   -0.20716800
 C                  0.86620700    4.84869700   -2.54287900
 C                 -1.24296100    4.80214100   -0.46575400
 H                  0.78821800    4.95963300    0.25059400
 H                  0.06949300    3.35564400    0.49452400
 C                 -0.53448500    5.46243800   -2.80555900
 H                  1.51761600    5.64334400   -2.15132200
 H                  1.30847900    4.47785400   -3.47106700
 C                 -1.17951400    5.93454500   -1.49754300
 H                 -1.64135900    5.16490500    0.48826300
 H                 -1.91889600    4.01414200   -0.81652100
 H                 -0.43011200    6.29077200   -3.51525200
 H                 -1.17046100    4.70488800   -3.28026300
 H                 -2.18649800    6.32068100   -1.69404100
 H                 -0.59199900    6.76702000   -1.08464500
 C                  3.25833100    1.38975500   -1.13652100
 H                  3.47830000    1.14332100   -2.17167300
 C                  4.11311900    1.03649500   -0.13289900
 H                  3.83134500    1.31024500    0.88363400
 C                  5.35216600    0.29176500   -0.25654500
 C                  6.07814800   -0.00432300    0.91645800
 C                  5.85481200   -0.17831500   -1.49084900
 C                  7.26372600   -0.73178200    0.86245000
 H                  5.69597200    0.34116000    1.87400800
 C                  7.03989400   -0.90358900   -1.54097300
 H                  5.31276500    0.02041800   -2.40961400
 C                  7.75064700   -1.18439700   -0.36715100
 H                  7.80702000   -0.94925400    1.77750700
 H                  7.41197700   -1.25883100   -2.49782700
 H                  8.67434100   -1.75409100   -0.41314700
 H                  1.41835300    2.26570600   -2.87931100
 O                 -0.31658500    1.21365900   -1.95965800
 C                 -1.36180600    1.66187200   -2.79165800
 H                 -0.94149200    2.17647100   -3.66940600
 H                 -1.94683700    0.80858200   -3.16138400
 H                 -2.05069900    2.35593300   -2.28846800

-Rh
LanL2DZ
****
-P -C -H -O -Cl -F
6-31G(d,p)
****

-Rh
LanL2DZ







