%nprocshared=12
%mem=2GB
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 C                  1.66955600   -2.86213000   -1.24660600
 C                  0.53765100   -0.04845500   -2.07573700
 H                  1.04708700   -3.06871100   -0.37958800
 C                  1.08622000   -2.90774900   -2.45807900
 C                  1.84480300    0.40299000   -2.22873400
 H                  2.28240000    0.38862200   -3.22618100
 C                  2.61754400    0.81309900   -1.15030000
 H                  2.16046300    0.76577900   -0.16800800
 C                  3.97272100    1.28267100   -1.17392800
 C                  4.58898600    1.57679000    0.06603900
 C                  4.72346000    1.44186200   -2.36439400
 C                  5.90396000    2.02575800    0.11543700
 H                  4.02225500    1.43537000    0.98132600
 C                  6.03391400    1.89321200   -2.30845900
 H                  4.27443100    1.21558500   -3.32530100
 C                  6.62589800    2.18680100   -1.07095600
 H                  6.36818500    2.24680400    1.07135100
 H                  6.60294000    2.01852000   -3.22435600
 H                  7.65297300    2.53814900   -1.03552500
 Rh                -0.69805800    0.04876600   -0.49322300
 O                 -2.25315000    0.53517100   -1.77326100
 O                  0.71185300   -0.42492200    0.96000000
 O                 -0.28628800    2.05951700   -0.19783700
 C                 -2.02787700   -2.40515000    0.26520900
 C                 -2.17974700   -3.93885100    0.17471500
 F                 -2.37014500   -4.32607800   -1.09810300
 F                 -1.04055400   -4.51410300    0.61891800
 F                 -3.19701300   -4.39084800    0.91568300
 O                 -1.25360500   -1.93789500   -0.61984200
 O                 -2.63042200   -1.82530700    1.19983100
 Rh                -2.35497300    0.24313400    1.41145800
 O                 -3.78577100    0.58725000   -0.07883000
 O                 -1.88005500    2.28351300    1.42551000
 O                 -0.73350500   -0.09211000    2.69615100
 C                 -3.40965600    0.66511600   -1.27211700
 C                  0.38573500   -0.31812800    2.17902600
 C                 -4.49556000    0.96938400   -2.32821900
 F                 -4.54482900   -0.02451200   -3.23538800
 F                 -4.19622300    2.11124700   -2.97611900
 F                 -5.70764800    1.10076100   -1.77783200
 C                  1.56129500   -0.53913600    3.15933400
 F                  1.31070400   -0.01146700    4.36168100
 F                  2.69470100    0.00899100    2.68128300
 F                  1.77577900   -1.86363700    3.31447700
 C                 -0.97417700    2.68992800    0.65952400
 C                 -0.60148000    4.18686500    0.74619800
 F                 -1.35382100    4.84175600    1.63729300
 F                  0.69096800    4.31248300    1.10565800
 F                 -0.75847200    4.77142900   -0.45595100
 H                  0.02889500   -0.37396200   -2.98731600
 H                  0.03833000   -3.17354400   -2.54486200
 H                  1.62264000   -2.70304400   -3.38021500
 C                  3.05323900   -2.49082700   -0.94751500
 C                  3.41054500   -2.26849400    0.39601800
 C                  4.03867800   -2.30492100   -1.93851500
 C                  4.69743100   -1.86170500    0.74193900
 H                  2.66118000   -2.40630900    1.16630700
 C                  5.32672100   -1.90665500   -1.59277200
 H                  3.79538300   -2.47626900   -2.98258600
 C                  5.66145800   -1.67765600   -0.25212300
 H                  4.94043200   -1.67665900    1.78414300
 H                  6.07363200   -1.76623900   -2.36861900
 H                  6.66376300   -1.35321600    0.01076500

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





