%nprocshared=20
%mem=2GB
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 C                 -0.73623800    1.25696600   -1.62782800
 C                 -2.13787800    0.91274000   -1.79196600
 H                 -2.56413200    0.99852500   -2.79114300
 C                 -2.90085800    0.44714400   -0.77057900
 H                 -2.43433000    0.34911400    0.20388900
 C                 -4.29421200    0.01924600   -0.81995100
 C                 -4.84233500   -0.57786200    0.33356900
 C                 -5.11711300    0.17333700   -1.95477900
 C                 -6.16528100   -1.01512900    0.35165300
 H                 -4.21604700   -0.69582100    1.21419400
 C                 -6.43844700   -0.26302100   -1.93329900
 H                 -4.72265400    0.64054900   -2.85182300
 C                 -6.96738900   -0.85965800   -0.78210300
 H                 -6.57105400   -1.47518500    1.24800600
 H                 -7.06175200   -0.13635500   -2.81393600
 H                 -7.99962400   -1.19751600   -0.77025400
 Rh                 0.49887400    0.13892000   -0.32449000
 O                  1.56947800   -0.62241500   -1.92697500
 O                 -0.47481900    0.79495800    1.37623700
 O                 -0.78194700   -1.49578400   -0.40713400
 C                  2.91382400    1.40064600    0.66136800
 C                  3.87538800    2.60311100    0.77741100
 F                  4.43479900    2.85609300   -0.42141600
 F                  3.19086100    3.69913100    1.15788000
 F                  4.85261700    2.38462500    1.66361900
 O                  1.94160800    1.61875500   -0.12000400
 O                  3.19430100    0.37649700    1.32789400
 Rh                 1.92965700   -1.28307200    1.18838800
 O                  2.90911500   -1.87693700   -0.56398400
 O                  0.51273000   -2.79784400    0.94992600
 O                  0.73579000   -0.55551400    2.76183100
 C                  2.51023400   -1.42798000   -1.66693400
 C                 -0.18544500    0.24701600    2.48012100
 C                  3.25677300   -1.91695500   -2.92799100
 F                  3.75423700   -0.86376400   -3.60413300
 F                  2.40182600   -2.56823200   -3.73964500
 F                  4.26644900   -2.74190700   -2.62850500
 C                 -1.18209800    0.60816600    3.60168800
 F                 -0.74734200    0.23409900    4.80898400
 F                 -2.35246600   -0.02317100    3.35453500
 F                 -1.42211100    1.93048000    3.62071100
 C                 -0.49892200   -2.53468500    0.25361300
 C                 -1.61306000   -3.60255000    0.19642400
 F                 -1.26053000   -4.73503200    0.81596100
 F                 -2.72063100   -3.11710900    0.79549600
 F                 -1.92295400   -3.89193400   -1.07930000
 H                 -0.19407800    1.31932600   -2.57291900
 C                 -1.50255800    4.06797200   -2.89621400
 C                 -0.43387000    3.46344500   -2.03931300
 C                 -0.64725500    3.09707100   -0.72211300
 C                 -1.91935000    3.45816700    0.00419500
 C                 -3.05902800    3.94993300   -0.90508800
 C                 -2.53695800    4.83001300   -2.04700100
 H                  0.22071900    2.92681200   -0.09807000
 H                  0.57094900    3.37842300   -2.44529800
 H                 -2.06453600    5.73179300   -1.63713300
 H                 -2.23848700    2.62047900    0.63155700
 H                 -1.63001700    4.25561800    0.70352400
 H                 -3.78802900    4.50039800   -0.30095000
 H                 -3.58670700    3.09192100   -1.33227600
 H                 -3.36287500    5.16140500   -2.68480700
 H                 -2.00119800    3.27176200   -3.46812300
 H                 -1.03048000    4.71956600   -3.63915300

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





