%nprocshared=20
%mem=8GB
%chk=CGMM_00015_TS7_spbs.chk
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                -0.43521700    0.00551200   -0.24471100
 O                 -2.23928000   -0.34525200   -1.20677200
 O                  1.31776100    0.15393000    0.90452200
 O                 -1.33029300    1.16944300    1.22025800
 C                  0.53823900   -2.54627100   -1.21292600
 C                  1.36618800   -3.40542000   -2.19300800
 F                  0.78809700   -3.40610900   -3.40716200
 F                  2.60235200   -2.87569400   -2.32326000
 F                  1.49072100   -4.66869400   -1.77673600
 O                  0.45414800   -1.33481200   -1.55763300
 O                  0.06142900   -3.12641900   -0.20519300
 Rh                -0.96839900   -1.96396600    1.19372700
 O                 -2.74246500   -2.13848900    0.10520200
 O                 -1.92900700   -0.63475700    2.47842600
 O                  0.81745900   -1.66239400    2.19016900
 C                 -2.96390400   -1.29687600   -0.80012000
 C                  1.52956500   -0.68971700    1.81257500
 C                 -4.33640900   -1.37228100   -1.50169900
 F                 -4.19652400   -1.25939900   -2.83285100
 F                 -5.10070000   -0.34588400   -1.07248700
 F                 -4.97522900   -2.51603700   -1.23423600
 C                  2.87475400   -0.56562400    2.56192400
 F                  3.69298400   -1.56102600    2.16487600
 F                  2.68748300   -0.68390200    3.88817800
 F                  3.47997800    0.60258400    2.32267400
 C                 -1.88038900    0.59208400    2.19453500
 C                 -2.66333300    1.51557100    3.15299100
 F                 -2.51198000    1.13269900    4.42888000
 F                 -2.27097000    2.79324700    3.04136100
 F                 -3.97504800    1.45148000    2.84346200
 C                  0.00790200    2.88940300   -2.75419300
 C                  0.57439400    4.16851000   -2.21768100
 C                  0.74313200    1.65299600   -2.25975100
 C                 -1.16167000    2.38657900   -1.97259700
 C                  0.06839000    4.80519000   -1.13517900
 C                 -1.13114900    4.29309200   -0.50016300
 C                 -1.75618400    3.14661200   -0.91584200
 H                  0.51488800    0.75451400   -2.82372400
 C                  1.97617600    1.71970000   -1.54114000
 H                  2.21831700    2.66192200   -1.05966300
 C                  2.85356300    0.67863200   -1.48377700
 H                  2.54970400   -0.26856900   -1.92070800
 C                  4.15525600    0.68059500   -0.83599800
 C                  4.81765400   -0.55280000   -0.65937400
 C                  4.77344100    1.84714600   -0.33449200
 C                  6.03766300   -0.62230400    0.01019700
 H                  4.35149900   -1.45967100   -1.03591200
 C                  5.99343700    1.77444300    0.32898700
 H                  4.29668700    2.81321000   -0.47004400
 C                  6.63093000    0.54014800    0.50909100
 H                  6.52407000   -1.58412500    0.14644000
 H                  6.45355500    2.68245600    0.70899500
 H                  7.58260700    0.48861400    1.03013100
 C                 -0.17367300    2.91451400   -4.27799000
 H                 -0.86309700    3.71516000   -4.56611300
 H                  0.78904000    3.08542100   -4.77141000
 H                 -0.57980200    1.96212600   -4.63410400
 H                  1.43442800    4.57597300   -2.74397000
 H                 -1.57670200    4.88222400    0.29825200
 H                 -1.73308800    1.58474700   -2.42519900
 C                  0.66846400    6.07629400   -0.59182800
 C                 -3.12238100    2.76391700   -0.39929500
 H                  0.99234000    5.93744100    0.44684100
 H                  1.53258500    6.39884900   -1.17894600
 H                 -0.06974100    6.88733400   -0.58849600
 H                 -3.27831200    3.12868500    0.61798900
 H                 -3.89372900    3.21382500   -1.03808200
 H                 -3.28134400    1.68608400   -0.41364100

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





