%nprocshared=20
%mem=8GB
#p opt=(maxstep=5) freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.24072500   -0.25547400   -0.24827800
 O                 -1.55100200   -1.18573900   -0.74828400
 O                  2.08018200    0.44934000    0.43939400
 O                 -0.60656100    0.74700100    1.37640100
 C                  1.55480700   -2.54447500   -1.40809000
 C                  2.19001900   -3.30590400   -2.59208200
 F                  1.30006800   -3.41667100   -3.59805100
 F                  3.25823900   -2.62821100   -3.05766000
 F                  2.59086800   -4.53700200   -2.24845500
 O                  1.17390200   -1.37936300   -1.71853500
 O                  1.49280000   -3.15842400   -0.31411700
 Rh                 0.61830000   -2.21107700    1.34551600
 O                 -1.26493800   -2.89529200    0.74140800
 O                 -0.27527400   -0.99615600    2.81931400
 O                  2.45744100   -1.30621500    1.84623700
 C                 -1.88292800   -2.23459400   -0.13306400
 C                  2.71402900   -0.19953400    1.32395800
 C                 -3.30400200   -2.72827300   -0.48380100
 F                 -3.56658700   -2.56216700   -1.79403200
 F                 -4.20573300   -2.00605000    0.21361700
 F                 -3.47700800   -4.02216900   -0.18164600
 C                  3.97253700    0.55532000    1.79927300
 F                  4.62828900   -0.09599400    2.76508100
 F                  3.61028900    1.76920900    2.27240000
 F                  4.81336200    0.75360600    0.76611000
 C                 -0.61947400    0.16710900    2.50075600
 C                 -1.10582800    1.09338900    3.63655000
 F                 -2.29513300    1.63978100    3.32947900
 F                 -1.22058900    0.45429700    4.80633700
 F                 -0.21505700    2.10257900    3.79261200
 C                  1.07131200    3.00239900   -0.31885100
 C                 -0.19625700    1.38564500   -1.63659800
 H                  1.00798300    2.30154000    0.51380900
 H                 -0.17729300    0.84308200   -2.58598300
 C                  0.84391100    2.53632200   -1.69458800
 C                  2.24207800    1.98675500   -2.20987400
 C                  0.36127100    3.65801900   -2.66772500
 C                  3.25529600    3.08774000   -2.52891500
 H                  1.98388700    1.43709100   -3.12315900
 H                  2.65400300    1.26893800   -1.50316500
 C                  1.40473200    4.71839400   -3.05150700
 H                  0.03569100    3.13255500   -3.57222400
 H                 -0.53110400    4.12883200   -2.24176700
 C                  2.70584500    4.08553100   -3.55461000
 H                  4.16814500    2.61192000   -2.90350800
 H                  3.53914500    3.61782800   -1.60873800
 H                  0.97005400    5.36211900   -3.82438400
 H                  1.62047200    5.36336400   -2.19245600
 H                  3.44853800    4.86208900   -3.76782500
 H                  2.51446400    3.55548900   -4.49819000
 O                  1.36272200    4.20570000   -0.04311300
 C                  1.64295000    4.57442100    1.35794100
 H                  2.72753100    4.63144100    1.45132400
 H                  1.18401000    5.55169200    1.49770600
 H                  1.21337700    3.82939600    2.03026300
 C                 -1.54039000    1.82446500   -1.25049900
 H                 -1.59270000    2.57116700   -0.45594100
 C                 -2.69277100    1.29138500   -1.71657100
 H                 -2.62050300    0.49924500   -2.45929200
 C                 -4.04457300    1.58671900   -1.23970100
 C                 -5.07433300    0.65656600   -1.49370400
 C                 -4.37222600    2.75427200   -0.51902400
 C                 -6.37315100    0.87693300   -1.03634400
 H                 -4.83888600   -0.25559500   -2.03435700
 C                 -5.67080200    2.97340500   -0.06475100
 H                 -3.60789000    3.50251200   -0.33015500
 C                 -6.67937600    2.03576000   -0.31805300
 H                 -7.14616600    0.14028300   -1.23838700
 H                 -5.90156700    3.88225500    0.48482600
 H                 -7.69063400    2.21125400    0.03539100

-Rh
LanL2DZ
****
-P -C -H -O -Cl -F
6-31G(d,p)
****

-Rh
LanL2DZ







