%nprocshared=20
%mem=2GB
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 C                 -0.77264700    0.41849000   -1.93933000
 C                 -2.11315400    0.07452100   -2.07982400
 H                 -2.66242200    0.46739500   -2.93413300
 C                 -2.77375100   -0.72232800   -1.15170500
 H                 -2.18914800   -1.11610800   -0.32874100
 C                 -4.15707300   -1.09476800   -1.14701100
 C                 -4.59394200   -1.98073700   -0.13098300
 C                 -5.10007500   -0.60840600   -2.08709000
 C                 -5.92549400   -2.36810000   -0.05680500
 H                 -3.86801300   -2.36487200    0.58038800
 C                 -6.42927700   -0.99520700   -2.00241000
 H                 -4.78658800    0.07222000   -2.87074400
 C                 -6.84376300   -1.87303200   -0.98976300
 H                 -6.25262200   -3.04994000    0.72158700
 H                 -7.15060400   -0.61726400   -2.71995700
 H                 -7.88659600   -2.17062000   -0.93040700
 Rh                 0.52831800   -0.08854700   -0.50647900
 O                  2.00971600   -0.61632600   -1.85771200
 O                 -0.81493600    0.36728800    0.99828700
 O                 -0.09934900   -2.05678500   -0.39493200
 C                  2.19827700    2.10701000    0.36571500
 C                  2.54704100    3.61068700    0.39467600
 F                  2.65596100    4.10274100   -0.85113200
 F                  1.54827900    4.27167000    1.01792800
 F                  3.68768000    3.85105800    1.05055700
 O                  1.29121800    1.83074700   -0.47207800
 O                  2.79358200    1.36667100    1.18484600
 Rh                 2.17065000   -0.62792800    1.34257600
 O                  3.47914900   -1.17189500   -0.19589600
 O                  1.30001400   -2.54080700    1.34416700
 O                  0.68124800   -0.00253100    2.68239400
 C                  3.10957700   -1.03315900   -1.38643200
 C                 -0.42479500    0.34001300    2.20280100
 C                  4.12658900   -1.42700000   -2.48148600
 F                  4.35192300   -0.38080100   -3.29764900
 F                  3.63099700   -2.43652000   -3.22252300
 F                  5.29565400   -1.81828200   -1.96213500
 C                 -1.49084000    0.86445000    3.18932600
 F                 -1.18792400    0.57458500    4.45883000
 F                 -2.69734600    0.34109400    2.90576300
 F                 -1.57940300    2.20573200    3.06668400
 C                  0.37519100   -2.77784100    0.53374600
 C                 -0.37015200   -4.12183300    0.68165000
 F                  0.22934600   -4.93978700    1.55206000
 F                 -1.62320800   -3.87200000    1.12618300
 F                 -0.46736000   -4.74846300   -0.50200900
 H                 -0.35215600    1.06062900   -2.71820900
 C                 -2.27601700    3.98167500   -2.46686600
 C                 -1.26569000    3.59686000   -1.41460600
 C                 -1.61053800    3.09860600   -0.21845400
 C                 -3.02896300    2.80800100    0.19359400
 C                 -4.02415400    2.93683600   -0.97192200
 C                 -3.68436600    4.13387500   -1.86965800
 H                 -0.83466100    2.87788300    0.50688000
 H                 -0.21177600    3.74869000   -1.63898000
 H                 -3.72312900    5.05595300   -1.27406200
 H                 -3.07195900    1.79832900    0.62205000
 H                 -3.30957800    3.48460800    1.01495700
 H                 -5.04740000    3.01575200   -0.58721400
 H                 -3.98721100    2.02371300   -1.57757700
 H                 -4.42642800    4.23909700   -2.66971200
 H                 -2.28728600    3.22047900   -3.26295600
 H                 -1.96445600    4.91357000   -2.95616200

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





