%nprocshared=20
%mem=2GB
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.58771300    1.81139500    1.58277600
 O                  0.60630400    3.46368900    0.31007200
 O                  0.51890600    0.01912600    2.66502900
 O                 -1.49874000    1.94151000    1.68718600
 C                  2.99617200    0.85833500    0.26294400
 C                  4.52038500    0.62780900    0.15896700
 F                  5.20290600    1.73859000    0.47525900
 F                  4.87775100   -0.34456400    1.02795000
 F                  4.88748400    0.23967500   -1.07140500
 O                  2.63465600    1.53280000    1.26250800
 O                  2.30588100    0.30665000   -0.63706800
 Rh                 0.23550000    0.42372200   -0.47638000
 O                  0.25284500    2.19227400   -1.55482900
 O                 -1.80744000    0.64538800   -0.16698400
 O                  0.24563200   -1.24056600    0.78191100
 C                  0.42772400    3.27027100   -0.91929500
 C                  0.36358100   -1.04926300    2.02373400
 C                  0.38039900    4.52692500   -1.81594100
 F                  0.70525600    5.63763000   -1.14311000
 F                 -0.86539700    4.67929100   -2.30895700
 F                  1.22571200    4.39630900   -2.85413100
 C                  0.35174900   -2.34381700    2.86711600
 F                  1.57514100   -2.91415200    2.83571200
 F                 -0.52875100   -3.23770900    2.36732200
 F                  0.02919200   -2.10915700    4.14277900
 C                 -2.18061000    1.35009100    0.81073500
 C                 -3.70997800    1.48032800    0.99000200
 F                 -4.11653200    0.64030800    1.96794300
 F                 -4.04537700    2.72886100    1.35238300
 F                 -4.37447800    1.17273800   -0.13140700
 C                  0.48646800   -3.73691500   -2.00732200
 C                 -0.55472100   -3.41399700   -1.12340300
 H                 -0.33993700   -3.38132500   -0.06286600
 C                  1.77559900   -3.99849300   -1.59980700
 C                  2.23376400   -4.10472600   -0.17604800
 C                  2.88182200   -4.09593900   -2.60435200
 C                  3.29736600   -3.01807500    0.12851600
 H                  2.70603800   -5.09064400   -0.05985200
 H                  1.41857900   -4.05211000    0.54420100
 C                  3.93198300   -2.98627700   -2.31748800
 H                  3.37779900   -5.07114100   -2.49739100
 H                  2.50002800   -4.01569300   -3.62585200
 C                  4.45156100   -3.07665100   -0.87803100
 H                  3.65767600   -3.15606600    1.15266600
 H                  2.81208100   -2.03869000    0.08360900
 H                  4.75027400   -3.08234500   -3.03920900
 H                  3.46605400   -2.00652500   -2.47814500
 H                  5.15528700   -2.26217600   -0.68323900
 H                  5.00224400   -4.01842700   -0.74802100
 C                 -1.87087000   -3.10721200   -1.50098000
 H                 -2.14127000   -3.13511300   -2.55177000
 C                 -2.76715000   -2.71179500   -0.53582000
 H                 -2.40421900   -2.69013400    0.49045700
 C                 -4.13482400   -2.29436500   -0.71220900
 C                 -4.86880000   -1.92835000    0.43820400
 C                 -4.76419700   -2.21355400   -1.97743500
 C                 -6.18595700   -1.49555600    0.33331900
 H                 -4.38521500   -1.97192500    1.40917500
 C                 -6.07972100   -1.78243100   -2.07592300
 H                 -4.21741800   -2.48008700   -2.87570900
 C                 -6.79387200   -1.42392600   -0.92298200
 H                 -6.73494400   -1.20727600    1.22421900
 H                 -6.55650800   -1.71932600   -3.04921700
 H                 -7.82169500   -1.08371600   -1.00913000
 H                  0.27953700   -3.69847600   -3.07392600
 O                  0.03411600   -0.74039300   -2.15193000
 C                 -1.02971200   -0.36878800   -2.97206400
 H                 -1.01202100   -0.98488700   -3.88899200
 H                 -2.01955200   -0.51560500   -2.50325500
 H                 -0.97981000    0.68541900   -3.30240400

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





