%nprocshared=20
%mem=8GB
#p opt=(ts,noeigentest,calcfc) freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.45881300   -0.00855200   -0.12246800
 O                 -0.87164000   -0.60276300   -1.59803200
 O                  1.88384500    0.30151100    1.37197600
 O                 -1.04706200    0.03918900    1.30614300
 C                  2.48349800   -1.39120600   -1.63404100
 C                  3.61575400   -1.45194700   -2.68265700
 F                  3.15073400   -1.05110900   -3.88064200
 F                  4.61274900   -0.62172300   -2.32164200
 F                  4.11763100   -2.68465000   -2.81308200
 O                  1.99518800   -0.23341900   -1.49308800
 O                  2.18821100   -2.46702400   -1.05415300
 Rh                 0.68712900   -2.44591900    0.40067600
 O                 -0.76974300   -2.80906600   -1.04481900
 O                 -0.83930500   -2.17610300    1.80719100
 O                  2.10232300   -1.91719600    1.83792000
 C                 -1.21016600   -1.81293200   -1.67630900
 C                  2.36393900   -0.69820700    1.97765100
 C                 -2.38607500   -2.09414300   -2.63706600
 F                 -2.49409800   -1.14262000   -3.57852700
 F                 -3.53141600   -2.11078600   -1.92600300
 F                 -2.24793600   -3.28078700   -3.24513300
 C                  3.42653000   -0.31943900    3.03175100
 F                  3.88270300   -1.38484600    3.69581400
 F                  2.89728500    0.54445000    3.92277500
 F                  4.46468600    0.28949800    2.42891000
 C                 -1.33159700   -1.02378500    1.92283500
 C                 -2.48731800   -0.89037700    2.93938700
 F                 -3.64650800   -1.23246200    2.34660500
 F                 -2.29956500   -1.69478200    3.99570700
 F                 -2.60016000    0.37337800    3.38549100
 C                  0.94886400    2.90057400    0.42493700
 C                 -0.24930200    2.21124800   -1.05882900
 H                  1.84159000    2.30369500    0.58029200
 H                 -0.01840000    1.68456100   -1.98203500
 C                  0.62206700    3.46697700   -0.88400100
 C                  1.82960200    3.44450800   -1.83484000
 C                 -0.09250300    4.82570000   -0.89959900
 C                  2.80374400    4.59159000   -1.53269800
 H                  1.44226800    3.53850800   -2.85750200
 H                  2.33357200    2.47259000   -1.77391200
 C                  0.89220600    5.96802700   -0.60104100
 H                 -0.52973500    4.95478300   -1.89716900
 H                 -0.91686600    4.83357300   -0.18266100
 C                  2.08976000    5.95066000   -1.56183200
 H                  3.62929000    4.57327900   -2.25304400
 H                  3.24723600    4.43540200   -0.53880100
 H                  0.36649700    6.92795200   -0.65937600
 H                  1.25315100    5.86704500    0.43198200
 H                  2.79139200    6.75363100   -1.30739400
 H                  1.73557600    6.14898100   -2.58324800
 O                  0.25810900    3.28382100    1.47093400
 C                  0.45850200    2.61379500    2.74502700
 H                  1.50901100    2.35647000    2.88234400
 H                  0.13573800    3.32947900    3.50083900
 H                 -0.16535600    1.71999800    2.77538300
 C                 -1.62321000    2.20140500   -0.59677500
 H                 -1.80833800    2.65041700    0.37564300
 C                 -2.64298600    1.59549600   -1.25054800
 H                 -2.45572100    1.18947600   -2.24041100
 C                 -3.98237100    1.35332600   -0.71812500
 C                 -4.99748900    0.91064600   -1.59129500
 C                 -4.29487900    1.47443200    0.65294300
 C                 -6.28132400    0.63614300   -1.12258300
 H                 -4.76474300    0.77705800   -2.64490000
 C                 -5.57722700    1.19735700    1.11923100
 H                 -3.51857900    1.74243400    1.36151200
 C                 -6.58029800    0.78407300    0.23495900
 H                 -7.04752300    0.29897600   -1.81547900
 H                 -5.79013100    1.28311200    2.18140700
 H                 -7.57800100    0.56256700    0.60326500

-Rh
LanL2DZ
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-P -C -H -O -Cl -F
6-31G(d,p)
****

-Rh
LanL2DZ








