%nprocshared=20
%mem=2GB
%chk=CGMM_0037_Rh2TFA4_cyc_exo.chk
#p opt freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.00890000    0.00390900    1.22856500
 O                  1.42836900    1.51184500    1.14615400
 O                 -1.41153500   -1.50430600    1.15143300
 O                 -1.50008600    1.42219800    1.16894500
 C                  1.90481600   -1.78190100   -0.01636700
 C                  2.99000600   -2.88161300   -0.00345500
 F                  3.99156500   -2.53216600    0.81758300
 F                  2.44820200   -4.02722200    0.44956000
 F                  3.48910500   -3.09719800   -1.22414000
 O                  1.51734800   -1.41496000    1.12764500
 O                  1.50870300   -1.39050400   -1.14749900
 Rh                -0.00959500    0.01742200   -1.20371800
 O                  1.39740400    1.53612900   -1.12852600
 O                 -1.52982500    1.42252700   -1.10614700
 O                 -1.41471200   -1.50251900   -1.12361900
 C                  1.79254900    1.91498200    0.00885100
 C                 -1.78970100   -1.89737000    0.01544300
 C                  2.89641900    2.99567800   -0.01978000
 F                  4.05006300    2.43231900   -0.42393100
 F                  3.08500300    3.53921700    1.18655500
 F                  2.57241200    3.96704400   -0.88552200
 C                 -2.86098500   -3.01012900   -0.01710900
 F                 -2.38798900   -4.07104400   -0.69173900
 F                 -3.95725200   -2.55813200   -0.64991500
 F                 -3.20582700   -3.40165300    1.21275500
 C                 -1.90908300    1.79853200    0.03743600
 C                 -3.02512300    2.86663600    0.01847000
 F                 -4.09102400    2.39531500   -0.64931700
 F                 -3.40671300    3.20599500    1.25299600
 F                 -2.57948100    3.96618800   -0.61334400
 C                  0.24165348   -0.46057808   -4.65437410
 C                 -0.90864316   -1.10031164   -5.43707998
 H                 -1.82768547   -1.19953659   -4.86096995
 C                  0.25663843   -1.93774225   -4.87444629
 C                 -0.05454590   -2.84821495   -3.69236630
 C                  1.31939674   -2.51318020   -5.80312206
 C                  1.22628169   -3.18981797   -2.91305265
 H                 -0.51012450   -3.77291240   -4.07385368
 H                 -0.78426342   -2.37215062   -3.03132180
 C                  2.59636892   -2.86069617   -5.01864355
 H                  0.92135593   -3.42017600   -6.27971901
 H                  1.55694911   -1.81148505   -6.60915693
 C                  2.29633474   -3.79253846   -3.83536712
 H                  0.99358239   -3.88103183   -2.09377631
 H                  1.61479744   -2.26989141   -2.45581374
 H                  3.33375801   -3.31754177   -5.68973044
 H                  3.04363091   -1.93087631   -4.64014602
 H                  3.21456014   -3.99813278   -3.27172790
 H                  1.93786179   -4.75858099   -4.21944746
 C                 -1.09552112   -0.83956579   -6.87272228
 H                 -0.19259532   -0.65224553   -7.45046038
 C                 -2.29579411   -0.81194276   -7.48335372
 H                 -3.18258984   -1.00276580   -6.87791985
 C                 -2.56198022   -0.54666346   -8.90398436
 C                 -3.89558647   -0.55603000   -9.35876238
 C                 -1.54937077   -0.27924382   -9.84933014
 C                 -4.20843782   -0.31019811  -10.69607529
 H                 -4.69374274   -0.76031618   -8.64886600
 C                 -1.86199801   -0.03363743  -11.18425088
 H                 -0.50840831   -0.26440096   -9.54017880
 C                 -3.19286545   -0.04646595  -11.61778546
 H                 -5.24660846   -0.32410029  -11.01715788
 H                 -1.06301912    0.17004159  -11.89235510
 H                 -3.43193549    0.14616309  -12.65976233
 H                  0.94149957    0.14725805   -5.23521927
 O                 -0.00010425    0.01624979   -3.36473594
 C                 -0.64581799    1.28436424   -3.36386117
 H                 -1.62015675    1.24215785   -3.87090385
 H                 -0.79836124    1.56924525   -2.31927747
 H                 -0.03085634    2.05279205   -3.85605978

-Rh
LanL2DZ
****
-P -C -H -O -Cl -F
6-31G(d,p)
****

-Rh 
LanL2DZ




 