%nprocshared=20
%mem=2GB
# opt=(ts,noeigentest,calcfc,maxstep=5) freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3

Title Card Required

0 1
 Rh                 0.87872800   -0.04063900   -0.44058200
 O                  2.70157300    0.48641800    0.39797100
 O                 -0.95867400   -0.68926700   -1.14905400
 O                  1.79082000   -1.63493200   -1.39382100
 C                 -0.42239100    1.12721200    1.89176500
 C                 -1.06735500    2.25510300    2.72948400
 F                 -1.17354700    3.40530300    2.04045900
 F                 -2.30853400    1.89178300    3.11755500
 F                 -0.33850000    2.49018200    3.83101600
 O                 -0.03663700    1.43692400    0.73373000
 O                 -0.36105400    0.02614500    2.49749300
 Rh                 0.53618400   -1.56701100    1.51331600
 O                  2.40554200   -0.90856500    2.18366900
 O                  1.46475500   -3.04517600    0.37002200
 O                 -1.29732200   -2.06451700    0.64088300
 C                  3.02284700   -0.05885200    1.49105600
 C                 -1.58724400   -1.54422400   -0.46789200
 C                  4.39233000    0.41205800    2.02829200
 F                  5.36138800    0.09897500    1.14716400
 F                  4.69402200   -0.15038800    3.20490500
 F                  4.38773000    1.74958800    2.18601800
 C                 -2.87585400   -2.09056500   -1.12062800
 F                 -3.83357800   -2.30073000   -0.20571300
 F                 -2.59653400   -3.27063400   -1.71335000
 F                 -3.35376800   -1.25874600   -2.05900400
 C                  1.85911700   -2.73861400   -0.78274700
 C                  2.54173600   -3.85313700   -1.60511400
 F                  2.52565800   -5.02937300   -0.96696400
 F                  1.91536500   -4.00271900   -2.78701200
 F                  3.82311100   -3.51938300   -1.85085400
 C                 -1.18638900    2.94702500   -2.30307200
 C                 -1.96959900    2.65838700   -1.19960600
 H                 -1.52916700    2.62234900   -3.28251400
 H                 -1.63704700    2.99637700   -0.22676400
 C                  0.07233700    3.55328000   -2.22123300
 C                  0.79464900    3.91278200   -3.48301000
 C                  0.66645800    4.09932400   -0.95784100
 C                  2.32918300    3.80342400   -3.39643900
 H                  0.53093200    4.96968000   -3.66255700
 H                  0.39649100    3.34766400   -4.33004400
 C                  2.19878500    3.94756200   -0.88591400
 H                  0.42656500    5.17580900   -0.97280300
 H                  0.20491700    3.67839200   -0.06789600
 C                  2.87538400    4.49861000   -2.14485400
 H                  2.76480200    4.23289400   -4.30525800
 H                  2.59792600    2.74419700   -3.35947300
 H                  2.55596300    4.47106600    0.00806700
 H                  2.43711200    2.88665900   -0.77065900
 H                  3.96050300    4.35487300   -2.08309100
 H                  2.69968200    5.58179900   -2.21426600
 O                  1.23473300    1.17349100   -2.09487100
 C                  0.80997600    0.57674000   -3.28843000
 H                 -0.28778400    0.50850300   -3.37758200
 H                  1.17419900    1.16685700   -4.14524400
 H                  1.21293400   -0.44065800   -3.42004300
 C                 -3.15852400    1.89250500   -1.21716000
 H                 -3.53499000    1.52115900   -2.16570300
 C                 -3.74151000    1.54627000   -0.02632300
 H                 -3.27248900    1.92862000    0.87797300
 C                 -4.87409800    0.67624400    0.19626400
 C                 -5.11777900    0.23708700    1.51688800
 C                 -5.71732500    0.21762700   -0.84090100
 C                 -6.15551800   -0.64824300    1.79022600
 H                 -4.47043500    0.58649200    2.31670400
 C                 -6.76010400   -0.65569200   -0.55981100
 H                 -5.55554000    0.54962500   -1.86079500
 C                 -6.97880800   -1.09584000    0.75250100
 H                 -6.32500000   -0.98784000    2.80744400
 H                 -7.40575700   -1.00133600   -1.36149500
 H                 -7.79188700   -1.78423800    0.96376200

-Rh
LanL2DZ
****
-P -C -H -O -Cl -F
6-31G(d,p)
****

-Rh
LanL2DZ





