%nprocshared=12
%mem=2GB
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.67025400   -0.20287300   -0.47552400
 O                  2.61603600    0.29428400    0.02986400
 O                 -1.27186600   -0.84178600   -0.85332600
 O                  1.37817300   -1.88669400   -1.44451200
 C                 -0.31850100    1.16085200    1.89941000
 C                 -0.90628100    2.33686200    2.71389300
 F                 -0.81909200    3.51057500    2.06105800
 F                 -2.21614300    2.10520900    2.96349200
 F                 -0.27720900    2.46566200    3.88960100
 O                 -0.03463900    1.39781800    0.69469800
 O                 -0.22027300    0.09615700    2.56355600
 Rh                 0.59714800   -1.57344100    1.62331900
 O                  2.51561300   -0.82232100    2.01823800
 O                  1.42008100   -3.11552500    0.48041900
 O                 -1.30676000   -2.17792600    0.99920500
 C                  3.05182300   -0.08660300    1.15149500
 C                 -1.76055000   -1.70667900   -0.07683800
 C                  4.46339500    0.45608000    1.46368100
 F                  5.34937600   -0.03447800    0.57600800
 F                  4.87278400    0.12795200    2.69520500
 F                  4.47175300    1.80043600    1.35820300
 C                 -3.10894200   -2.32094900   -0.51398800
 F                 -4.03694800   -2.15791400    0.44584400
 F                 -2.95095800   -3.64376800   -0.72037600
 F                 -3.57056300   -1.77578900   -1.64776700
 C                  1.60304100   -2.91618800   -0.74714100
 C                  2.23572900   -4.08021800   -1.54078000
 F                  2.17163800   -5.23635300   -0.86765000
 F                  1.61827200   -4.24424000   -2.72321100
 F                  3.53327200   -3.80187100   -1.78172300
 C                 -0.80889800    3.46684100   -2.28061300
 C                 -1.64845600    3.10934900   -1.22622700
 H                 -1.11731100    3.21094600   -3.29094900
 H                 -1.34959100    3.35507600   -0.21466100
 C                  0.45974500    3.99289600   -2.10320000
 C                  1.36992500    4.17141900   -3.27551100
 C                  1.06759400    4.37165100   -0.78947600
 C                  2.69731800    3.39208700   -3.06088300
 H                  1.61028900    5.24234600   -3.35514100
 H                  0.88257100    3.86413900   -4.20462300
 C                  2.39120200    3.59644700   -0.56223300
 H                  1.29972100    5.44551800   -0.84212900
 H                  0.39769600    4.21754000    0.05452600
 C                  3.35994800    3.78126800   -1.73410600
 H                  3.36085200    3.59618800   -3.90808000
 H                  2.46158500    2.32350900   -3.04656500
 H                  2.83872900    3.94189700    0.37590000
 H                  2.15276400    2.53912000   -0.44597500
 H                  4.25216500    3.16502300   -1.56927600
 H                  3.69431900    4.82746200   -1.77787200
 O                  0.86288800    0.93842700   -2.16857900
 C                  0.10538200    0.50116400   -3.25194400
 H                 -0.98565100    0.60978900   -3.10641600
 H                  0.37174200    1.09963700   -4.14171000
 H                  0.29283600   -0.55545000   -3.52143700
 C                 -2.83459700    2.36869200   -1.36708300
 H                 -3.17109600    2.08819000   -2.36098400
 C                 -3.49063200    1.94370600   -0.23470000
 H                 -3.07063300    2.25626100    0.71778100
 C                 -4.65956800    1.11038300   -0.13779700
 C                 -5.10764000    0.75058700    1.15521000
 C                 -5.36603600    0.62950700   -1.26537800
 C                 -6.22661100   -0.05739600    1.31714800
 H                 -4.55813200    1.10838400    2.02158700
 C                 -6.48289300   -0.17665300   -1.09621500
 H                 -5.03482600    0.88703600   -2.26574300
 C                 -6.91568500   -0.52114200    0.19195600
 H                 -6.56011200   -0.33112300    2.31318400
 H                 -7.02025100   -0.54499600   -1.96460600
 H                 -7.78930600   -1.15440100    0.31567900

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





