%nprocshared=20
%mem=2GB
#p opt freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral=grid=ultrafine

Title Card Required

0 1
 Rh                 0.00890000    0.00390900    1.22856500
 O                  1.42836900    1.51184500    1.14615400
 O                 -1.41153500   -1.50430600    1.15143300
 O                 -1.50008600    1.42219800    1.16894500
 C                  1.90481600   -1.78190100   -0.01636700
 C                  2.99000600   -2.88161300   -0.00345500
 F                  3.99156500   -2.53216600    0.81758300
 F                  2.44820200   -4.02722200    0.44956000
 F                  3.48910500   -3.09719800   -1.22414000
 O                  1.51734800   -1.41496000    1.12764500
 O                  1.50870300   -1.39050400   -1.14749900
 Rh                -0.00959500    0.01742200   -1.20371800
 O                  1.39740400    1.53612900   -1.12852600
 O                 -1.52982500    1.42252700   -1.10614700
 O                 -1.41471200   -1.50251900   -1.12361900
 C                  1.79254900    1.91498200    0.00885100
 C                 -1.78970100   -1.89737000    0.01544300
 C                  2.89641900    2.99567800   -0.01978000
 F                  4.05006300    2.43231900   -0.42393100
 F                  3.08500300    3.53921700    1.18655500
 F                  2.57241200    3.96704400   -0.88552200
 C                 -2.86098500   -3.01012900   -0.01710900
 F                 -2.38798900   -4.07104400   -0.69173900
 F                 -3.95725200   -2.55813200   -0.64991500
 F                 -3.20582700   -3.40165300    1.21275500
 C                 -1.90908300    1.79853200    0.03743600
 C                 -3.02512300    2.86663600    0.01847000
 F                 -4.09102400    2.39531500   -0.64931700
 F                 -3.40671300    3.20599500    1.25299600
 F                 -2.57948100    3.96618800   -0.61334400
 C                 -2.35432380    1.92467489    5.93235697
 C                 -1.14627726    1.72205225    5.01663305
 H                 -0.40215592    2.51398968    5.08264121
 C                 -2.50069527    2.17302606    4.45135378
 C                 -0.56459744    0.39748008    4.74458597
 H                 -1.25532576   -0.43135074    4.62570535
 C                  0.75898342    0.16949299    4.64315871
 H                  1.43703215    1.01524875    4.76378583
 C                  1.41775649   -1.11850142    4.38340116
 C                  2.82308560   -1.15496273    4.28945114
 C                  0.71827060   -2.33298406    4.22128109
 C                  3.50367519   -2.34795764    4.04383348
 H                  3.38436958   -0.23149729    4.41175217
 C                  1.39796678   -3.52371262    3.97586299
 H                 -0.36558479   -2.34960264    4.28875448
 C                  2.79467226   -3.54055029    3.88476082
 H                  4.58837051   -2.34488394    3.97671597
 H                  0.83550437   -4.44587529    3.85514100
 H                  3.32052443   -4.47163531    3.69348958
 C                 -3.11299553    0.78632741    6.60925845
 C                 -3.38203775    1.24128189    3.61460086
 C                 -4.44959250    0.52876370    4.46168494
 C                 -3.81514327   -0.19936790    5.65176986
 H                 -3.10715076   -0.94896365    5.27724315
 H                 -3.86580336    1.82728049    2.82577310
 H                 -2.77115758    0.48775460    3.10146995
 H                 -5.00989096   -0.17749629    3.83740429
 H                 -5.17232625    1.26805244    4.83438883
 H                 -4.57683483   -0.75438914    6.21177426
 H                 -3.88671460    1.25196968    7.23331929
 H                 -2.45111302    0.24259090    7.29541163
 H                 -2.27163996    2.81248777    6.55624915
 H                 -2.51995531    3.21545027    4.14237493

-Rh
LanL2DZ
****
-P -C -H -O -Cl -F
6-31G(d,p)
****

-Rh
LanL2DZ







