%nprocshared=12
%mem=8GB
#p opt=(ts,noeigentest,calcfc) freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.38123600   -0.03188700   -0.03263300
 O                 -1.23260500    0.03972900    1.29201800
 O                  1.98076900   -0.32297600   -1.30612100
 O                  1.60679600    0.09838100    1.63250000
 C                 -1.25885800   -1.57371300   -1.86392700
 C                 -2.31601200   -1.73906000   -2.97704100
 F                 -2.48760800   -0.60651500   -3.67668100
 F                 -1.96241700   -2.71564400   -3.82741400
 F                 -3.49642800   -2.07039500   -2.41894100
 O                 -0.83639700   -0.40400400   -1.67493500
 O                 -0.97068600   -2.63830600   -1.25294700
 Rh                 0.36371900   -2.49167700    0.33139700
 O                 -1.25560100   -2.21718800    1.59924100
 O                  1.70797400   -2.16248800    1.89665900
 O                  1.97662500   -2.58268300   -0.99637400
 C                 -1.68252600   -1.04085700    1.75381100
 C                  2.40119200   -1.50200600   -1.47785600
 C                 -2.98551100   -0.91666200    2.57374500
 F                 -4.03376000   -1.11988100    1.75136700
 F                 -3.10932900    0.29914700    3.12434500
 F                 -3.03435500   -1.83333000    3.55227400
 C                  3.64784200   -1.57665600   -2.38493600
 F                  3.99666500   -2.83739700   -2.66021700
 F                  4.68043500   -0.97351400   -1.75963700
 F                  3.42476200   -0.93026600   -3.54137000
 C                  2.02025100   -0.97288500    2.15736100
 C                  3.13021900   -0.77689100    3.21175000
 F                  3.14008800   -1.76369600    4.11467000
 F                  4.32157200   -0.76895900    2.57385600
 F                  2.99510500    0.39382400    3.85254800
 C                  1.58150900    2.67122000    0.11133300
 C                 -0.05236500    2.40839800   -0.81893300
 H                  1.45249500    2.46904900    1.17198700
 H                  0.11506000    2.04083700   -1.82881000
 C                  0.76121100    3.68648000   -0.54166500
 C                  1.33848800    4.34080200   -1.80231400
 C                  0.14002900    4.71632800    0.41124400
 C                  2.33339500    5.45811000   -1.45320000
 H                  0.49612000    4.75559500   -2.37066200
 H                  1.81525900    3.58530400   -2.43346900
 C                  1.14578300    5.82908300    0.74625200
 H                 -0.74862000    5.13976000   -0.07380700
 H                 -0.19781700    4.23351400    1.33395700
 C                  1.69859400    6.49756000   -0.51946000
 H                  2.68947300    5.93325700   -2.37464100
 H                  3.20975400    5.01320800   -0.96366900
 H                  0.66567800    6.56948100    1.39642400
 H                  1.97808000    5.39625600    1.31952900
 H                  2.43121400    7.26824900   -0.25210200
 H                  0.87905100    7.00651500   -1.04651100
 O                  2.74344500    2.33513200   -0.45462500
 C                  3.72862000    1.61404500    0.31606600
 H                  3.61853000    1.82270600    1.38258300
 H                  3.65113800    0.54614000    0.12911700
 H                  4.69533000    1.97875200   -0.03617800
 C                 -1.41496200    2.32575700   -0.29616300
 H                 -1.55764500    2.61710000    0.73891300
 C                 -2.46982800    1.87243800   -1.00771800
 H                 -2.30026000    1.54453100   -2.02935600
 C                 -3.82341600    1.65053700   -0.49402800
 C                 -4.70410700    0.84534000   -1.24497400
 C                 -4.28245200    2.15989700    0.73849700
 C                 -5.98245900    0.54391800   -0.77587300
 H                 -4.36879100    0.44026600   -2.19518500
 C                 -5.56058000    1.86119400    1.20295200
 H                 -3.63540200    2.79506500    1.33577400
 C                 -6.41819500    1.04944800    0.45139800
 H                 -6.63737100   -0.08856700   -1.36918400
 H                 -5.89120800    2.26160700    2.15760800
 H                 -7.41335800    0.81565600    0.81884600

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LanL2DZ
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-P -C -H -O -Cl -F
6-31G(d,p)
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-Rh
LanL2DZ








