%nprocshared=20
%mem=2GB
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.20048900   -0.07679100   -0.20706800
 O                  1.59761100   -0.75560500   -1.57722600
 O                 -1.09246500    0.48785500    1.31283400
 O                 -1.09581500   -1.53994000   -0.88179600
 C                  2.39274700    0.80260500    1.45949600
 C                  3.47556900    1.82112900    1.87811100
 F                  4.42268100    1.86379900    0.91944100
 F                  2.95404700    3.04925900    2.01022400
 F                  4.05754900    1.47619800    3.03319500
 O                  1.57286000    1.23897500    0.60788200
 O                  2.47588600   -0.34608800    1.96964500
 Rh                 1.09607400   -1.76784800    1.35267000
 O                  2.40753000   -2.34378000   -0.15851500
 O                 -0.35774300   -3.07167100    0.63315000
 O                 -0.26634400   -1.07395400    2.75202900
 C                  2.35866500   -1.70555900   -1.24138500
 C                 -1.01831800   -0.11915700    2.41339300
 C                  3.34486200   -2.12150100   -2.35420600
 F                  4.02045100   -1.04274700   -2.79145100
 F                  2.65825000   -2.63483500   -3.39184200
 F                  4.22439500   -3.03383000   -1.93039000
 C                 -1.97913800    0.34944200    3.52881100
 F                 -2.70649300    1.40914200    3.15613200
 F                 -1.27454800    0.68027300    4.62488600
 F                 -2.81852400   -0.65136300    3.85267700
 C                 -1.10475100   -2.65251900   -0.29074700
 C                 -2.22531600   -3.62330400   -0.72283400
 F                 -3.21528100   -3.57895000    0.19144700
 F                 -2.73868000   -3.28601400   -1.91467400
 F                 -1.76963700   -4.88150100   -0.79324900
 C                 -3.42368000    0.11618400   -1.37490000
 C                 -3.53476100    1.52178500   -2.73276300
 C                 -2.35222500    0.77072500   -2.18254200
 H                 -3.67934200   -0.89271500   -1.68685500
 C                 -3.95894800    1.16646300   -4.13887000
 H                 -3.99671500    0.08092300   -4.27427600
 H                 -4.94549800    1.57286500   -4.38000900
 H                 -3.23539200    1.55649500   -4.86792700
 C                 -3.87078700    0.56640500   -0.11655300
 C                 -4.02352200    2.69749000   -2.11874600
 C                 -4.06156000    2.95789500   -0.75091000
 C                 -3.96989000    1.91689500    0.20411900
 H                 -4.50134000    3.41864900   -2.78126900
 H                 -4.19201200    2.17495800    1.23686700
 C                 -4.38816100    4.35349700   -0.26283900
 C                 -4.31188200   -0.49337000    0.87081200
 H                 -4.73734300   -0.05407100    1.77655800
 H                 -5.07125700   -1.14644900    0.42252500
 H                 -3.47967800   -1.14192900    1.16663300
 H                 -5.11325300    4.34001800    0.55886700
 H                 -3.48747100    4.85607500    0.11395100
 H                 -4.79319500    4.97747600   -1.06610800
 H                 -1.95137300    0.07964100   -2.92380600
 C                 -1.25073700    1.56249200   -1.55740400
 H                 -1.51224500    2.21849700   -0.73366100
 C                 -0.01640600    1.65843000   -2.14353200
 H                  0.19775300    0.99209000   -2.97872900
 C                  1.03509000    2.63257200   -1.83259100
 C                  2.34652100    2.37564300   -2.27393100
 C                  0.78740800    3.79228200   -1.07548300
 C                  3.38760800    3.24058700   -1.94379700
 H                  2.54895100    1.47046900   -2.83915500
 C                  1.82884000    4.65800700   -0.75251700
 H                 -0.22230900    4.01644000   -0.74469500
 C                  3.13253200    4.38308300   -1.17974900
 H                  4.39823800    3.02165300   -2.27623000
 H                  1.62580500    5.55003500   -0.16681700
 H                  3.94375700    5.05719200   -0.92021200

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





