%nprocshared=20
%mem=2GB
%chk=CGMM_0034_TS9opt.chk
#p opt=(ts,noeigentest,calcfc) freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 3.22311000    0.11030400    0.33452300
 O                  3.15235700   -1.36182700    1.79740500
 O                  3.09233900    1.55005800   -1.15882100
 O                  3.71593700   -1.32895900   -1.07331600
 C                  1.29956300    1.65042900    1.84654700
 C                  0.84875100    2.78022000    2.79898700
 F                  1.80074600    3.11036900    3.67216000
 F                  0.54446400    3.87066400    2.06015300
 F                 -0.25402300    2.42007300    3.48119400
 O                  2.54082000    1.51071400    1.70882000
 O                  0.35114900    1.03328200    1.27830600
 Rh                 0.86430300   -0.41097400   -0.12964700
 O                  0.95697300   -1.81790500    1.38268200
 O                  1.52716500   -1.81931800   -1.48055000
 O                  0.91614500    1.03710200   -1.60478300
 C                  2.06406700   -1.96508700    1.97805300
 C                  1.98919400    1.68692200   -1.75011600
 C                  2.03875600   -3.04973900    3.07864400
 F                  1.10099900   -2.74085700    3.99340500
 F                  3.21709400   -3.16111700    3.69631900
 F                  1.72333300   -4.23803000    2.53333100
 C                  1.92202300    2.86226100   -2.75123500
 F                  1.78990700    4.01124200   -2.05503100
 F                  0.86850200    2.75107200   -3.57349800
 F                  3.03707800    2.93527900   -3.48684900
 C                  2.77648800   -1.94954500   -1.63367300
 C                  3.16774000   -3.03555600   -2.66124200
 F                  2.64243200   -2.73181400   -3.86090300
 F                  4.49248800   -3.14574600   -2.78910400
 F                  2.67269600   -4.22340000   -2.26913800
 C                 -2.73270400    0.27887000    0.36268900
 C                 -3.85178500    0.19952400   -0.55787100
 H                 -3.59159400   -0.08166500   -1.57673400
 C                 -3.06297700    1.55971800   -0.20190000
 C                 -2.29077400    2.17148700   -1.37290400
 C                 -3.67862700    2.58575700    0.75157900
 C                 -1.28373300    3.21774200   -0.86557600
 H                 -3.01688900    2.64724900   -2.04434500
 H                 -1.76852300    1.38408900   -1.92136400
 C                 -2.64953300    3.62361700    1.21826800
 H                 -4.48766400    3.08025800    0.19538200
 H                 -4.14881400    2.09177800    1.60936800
 C                 -1.94081400    4.27864800    0.02551400
 H                 -0.79500100    3.67923300   -1.72842000
 H                 -0.50530400    2.70605500   -0.29491000
 H                 -3.15071700    4.37793000    1.83552300
 H                 -1.91029600    3.13099200    1.85669500
 H                 -1.18427800    4.98388100    0.38419600
 H                 -2.66885200    4.85915300   -0.55927800
 C                 -5.20416000   -0.16461900   -0.10859300
 H                 -5.45524000    0.06497800    0.92431000
 C                 -6.10391100   -0.75730800   -0.91665200
 H                 -5.80250400   -0.95250900   -1.94629400
 C                 -7.46644100   -1.17965600   -0.58184400
 C                 -8.27970500   -1.70605900   -1.60244300
 C                 -8.00551700   -1.09396400    0.71697600
 C                 -9.58251400   -2.12658700   -1.34153600
 H                 -7.88085600   -1.78414600   -2.61078200
 C                 -9.30614000   -1.51293500    0.97739100
 H                 -7.40217600   -0.70486000    1.53144200
 C                -10.10197500   -2.03114700   -0.04984900
 H                -10.19051300   -2.52974900   -2.14611400
 H                 -9.70206100   -1.44014600    1.98622400
 H                -11.11583600   -2.35978200    0.15813800
 H                 -2.59818900   -0.05719300    1.38430200
 O                 -1.11835700   -0.84502000   -0.67223200
 C                 -1.49521200   -2.19896700   -0.50322400
 H                 -2.53850800   -2.33339000   -0.81988900
 H                 -0.85518500   -2.81825200   -1.14508300
 H                 -1.38260800   -2.54256000    0.53381200

-Rh
LanL2DZ
****
-P -C -H -O -Cl -F
6-31G(d,p)
****

-Rh
LanL2DZ







