%nprocshared=20
%mem=8GB
# sp b3lyp/genecp scrf=(smd,solvent=dichloroethane) empiricaldispersion=gd3 integral(grid=ultrafine)

Title Card Required

0 1
 Rh                 0.24172500   -0.25547400   -0.24727800
 O                 -1.55200200   -1.18273900   -0.74628400
 O                  2.08518200    0.44134000    0.43639400
 O                 -0.60156100    0.74900100    1.37640100
 C                  1.55380700   -2.54547500   -1.40809000
 C                  2.19001900   -3.30690400   -2.59208200
 F                  1.30006800   -3.41767100   -3.59805100
 F                  3.25823900   -2.62821100   -3.05666000
 F                  2.59086800   -4.53700200   -2.24845500
 O                  1.17190200   -1.38036300   -1.71953500
 O                  1.49280000   -3.15842400   -0.31411700
 Rh                 0.61830000   -2.21207700    1.34551600
 O                 -1.26493800   -2.89529200    0.74040800
 O                 -0.27627400   -0.99615600    2.81831400
 O                  2.45744100   -1.30921500    1.85023700
 C                 -1.88292800   -2.23359400   -0.13206400
 C                  2.71602900   -0.20453400    1.32495800
 C                 -3.30400200   -2.72727300   -0.48380100
 F                 -3.56658700   -2.56116700   -1.79403200
 F                 -4.20673300   -2.00605000    0.21361700
 F                 -3.47700800   -4.02116900   -0.18164600
 C                  3.97353700    0.55232000    1.80127300
 F                  4.62928900   -0.09699400    2.76708100
 F                  3.60828900    1.76620900    2.27340000
 F                  4.81436200    0.75160600    0.76811000
 C                 -0.61747400    0.16810900    2.50075600
 C                 -1.10482800    1.09338900    3.63655000
 F                 -2.29413300    1.63978100    3.32847900
 F                 -1.22058900    0.45429700    4.80533700
 F                 -0.21505700    2.10257900    3.79361200
 C                  1.08631200    3.00239900   -0.32385100
 C                 -0.19525700    1.38764500   -1.63359800
 H                  1.08498300    2.28954000    0.49880900
 H                 -0.17529300    0.84508200   -2.58298300
 C                  0.84491100    2.54032200   -1.69758800
 C                  2.24207800    1.98675500   -2.21387400
 C                  0.36027100    3.66001900   -2.66772500
 C                  3.25529600    3.08774000   -2.53391500
 H                  1.98188700    1.43709100   -3.12615900
 H                  2.65400300    1.26893800   -1.50716500
 C                  1.40473200    4.72039400   -3.05250700
 H                  0.03269100    3.13655500   -3.57322400
 H                 -0.53010400    4.13283200   -2.24076700
 C                  2.70484500    4.08553100   -3.55861000
 H                  4.16814500    2.61192000   -2.91050800
 H                  3.54014500    3.61882800   -1.61473800
 H                  0.97005400    5.36611900   -3.82438400
 H                  1.62347200    5.36336400   -2.19345600
 H                  3.44753800    4.86208900   -3.77382500
 H                  2.51146400    3.55648900   -4.50219000
 O                  1.32772200    4.21370000   -0.04011300
 C                  1.63595000    4.57742100    1.35594100
 H                  2.72153100    4.64444100    1.42732400
 H                  1.17201000    5.54969200    1.51070600
 H                  1.22737700    3.82539600    2.03326300
 C                 -1.53939000    1.82646500   -1.24749900
 H                 -1.59270000    2.57216700   -0.45294100
 C                 -2.69077100    1.29338500   -1.71557100
 H                 -2.61750300    0.50224500   -2.45929200
 C                 -4.04357300    1.58771900   -1.23970100
 C                 -5.07233300    0.65756600   -1.49470400
 C                 -4.37222600    2.75527200   -0.51902400
 C                 -6.37115100    0.87693300   -1.03734400
 H                 -4.83588600   -0.25459500   -2.03535700
 C                 -5.67080200    2.97340500   -0.06475100
 H                 -3.60789000    3.50351200   -0.32915500
 C                 -6.67837600    2.03576000   -0.31905300
 H                 -7.14416600    0.14028300   -1.23938700
 H                 -5.90156700    3.88225500    0.48482600
 H                 -7.69063400    2.21025400    0.03439100

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****

-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857





