%mem=22GB
%nprocshared=12
#p b97d nosymm freq=noraman scrf=(solvent=n,n-DiMethylFormamide,smd) genecp opt

opt

-1 1
 C                 -7.46947900    4.97398700    0.81350100
 C                 -6.18043000    4.60114300    0.39716100
 C                 -5.05490400    4.82440400    1.22307900
 C                 -5.25716900    5.42882100    2.48234200
 C                 -6.54620400    5.80233500    2.90406900
 C                 -7.65983400    5.58001600    2.07146100
 H                 -8.32625700    4.78648900    0.16026700
 H                 -6.03840200    4.13010600   -0.57929000
 H                 -4.39180200    5.59148900    3.12705700
 H                 -6.68249200    6.26658000    3.88496700
 C                 -3.65957900    4.48423300    0.72821100
 H                 -3.74927000    3.59612000    0.06491700
 O                 -2.70883900    4.29446300    1.75709700
 Si                -2.98895100    5.95127600   -0.35390300
 C                 -1.29175000    5.49655900   -1.07857700
 H                 -0.85343100    6.36097700   -1.61082200
 H                 -1.36252600    4.66333300   -1.79861300
 C                 -2.86350500    7.50325700    0.73277100
 H                 -2.47975800    8.36560800    0.15831100
 H                 -2.17500500    7.32643300    1.57726900
 H                 -0.59039000    5.19697000   -0.28163800
 H                 -3.84228500    7.78833300    1.15471700
 Si                -2.11096900    2.61676200    2.23912000
 C                 -1.01344200    3.42874400    3.60346700
 H                  0.04972900    3.15748800    3.46359700
 H                 -1.30232100    3.05435200    4.60376400
 C                 -1.37814000    2.16869900    0.50969700
 H                 -0.27364000    2.23362700    0.54945400
 H                 -1.71781400    2.83482800   -0.29905000
 C                 -3.87122900    1.93633600    2.65066700
 H                 -4.63045300    2.30658400    1.94087300
 H                 -4.18012800    2.28450600    3.65529000
 H                 -1.62146300    1.12812400    0.22676000
 H                 -1.09114900    4.52943200    3.61215900
 H                 -3.91589000    0.83282500    2.65719400
 C                 -4.19962700    6.27983900   -1.78419800
 C                 -4.20952800    5.44488000   -2.92983300
 C                 -5.17501400    7.30502500   -1.71412700
 C                 -5.15404800    5.61860100   -3.95775500
 H                 -3.47149700    4.64230200   -3.02196900
 C                 -6.12317100    7.48784900   -2.73788200
 H                 -5.20115700    7.96778300   -0.84468600
 C                 -6.11678900    6.64172900   -3.86242700
 H                 -5.14019200    4.95893700   -4.82965100
 H                 -6.86671300    8.28555400   -2.65783100
 H                 -6.85317100    6.77899300   -4.65843500
 F                 -1.37338500    0.93608300    2.86738000
 H                 -8.66191700    5.86826700    2.39915000

C F H O Si 0
6-31+g(d)
****




