%nprocshared=8
%mem=2GB
# sp wb97xd/genecp scrf=(smd,solvent=dichloroethane)

Title Card Required

0 1
 Si                -0.39315100    0.08876500   -0.12415000
 C                 -0.91466900   -0.14227600    1.68582900
 C                 -0.88790400    1.77906400   -0.83003600
 C                 -0.91129600   -1.30898700   -1.30468100
 H                 -0.34364900    0.62603000    2.22802800
 H                 -0.23463300    1.90562200   -1.70599000
 H                 -0.86468700   -0.85203500   -2.30469900
 C                 -0.48456200   -1.51115100    2.23298600
 C                 -2.40397300    0.11904600    1.95304300
 C                  0.04525100   -2.51035400   -1.29857700
 C                 -2.35625300   -1.77953400   -1.07277900
 C                 -0.57744600    2.91730500    0.15189900
 C                 -2.33796600    1.85090700   -1.32924600
 H                 -0.27919300   -3.26192600   -2.02895400
 H                  1.07035400   -2.22169800   -1.55077600
 H                  0.07170400   -2.99848000   -0.31778400
 H                 -2.45206900   -2.30006900   -0.11341000
 H                 -3.07790400   -0.95631500   -1.07647400
 H                 -2.65905700   -2.48571300   -1.85572500
 H                 -2.62698100   -0.00953000    3.01970300
 H                 -2.69744500    1.13719100    1.67847500
 H                 -3.04688800   -0.57404500    1.40086600
 H                 -0.67613400   -1.57701200    3.31115200
 H                 -1.04018600   -2.32524900    1.75397100
 H                  0.58331600   -1.69827600    2.07532300
 H                 -3.05934900    1.70950300   -0.51674900
 H                 -2.54010600    2.83265100   -1.77550600
 H                 -2.54423900    1.09605800   -2.09515800
 H                  0.46501500    2.89344200    0.48915800
 H                 -0.75069800    3.89432500   -0.31574700
 H                 -1.21597700    2.86367000    1.04131100
 C                  1.46486000    0.11320800   -0.08143800
 C                  2.67839300    0.14286100   -0.04461000
 Cl                 4.32566600    0.17874200    0.00133800

-C -H -O -Si -N -F -Cl
6-311++G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh  
S   1   1.00
      2.6460000              1.0000000
S   1   1.00
      1.7510000              1.0000000
S   1   1.00
      0.5713000              1.0000000
S   1   1.00
      0.1438000              1.0000000
S   1   1.00
      0.0428000              1.0000000
P   1   1.00
      5.4400000              1.0000000
P   1   1.00
      1.3290000              1.0000000
P   1   1.00
      0.4845000              1.0000000
P   1   1.00
      0.0869000              1.0000000
P   1   1.00
      0.0257000              1.0000000
D   2   1.00
      3.6690000              0.0760059
      1.4230000              0.5158852
D   1   1.00
      0.5091000              1.0000000
D   1   1.00
      0.1610000              1.0000000
F   1   1.00
      1.3500000              1.0000000
****
-Ag     
S   1   1.00
      2.9500000              1.0000000
S   1   1.00
      2.1490000              1.0000000
S   1   1.00
      0.6684000              1.0000000
S   1   1.00
      0.0997000              1.0000000
S   1   1.00
      0.0347000              1.0000000
P   1   1.00
      6.5530000              1.0000000
P   1   1.00
      1.5650000              1.0000000
P   1   1.00
      0.5748000              1.0000000
P   1   1.00
      0.0833000              1.0000000
P   1   1.00
      0.0252000              1.0000000
D   2   1.00
      3.3910000              0.1396938
      1.5990000              0.4744421
D   1   1.00
      0.6282000              1.0000000
D   1   1.00
      0.2108000              1.0000000
F   1   1.00
      1.6110000              1.0000000
****

-Br
LANL2DZ
-Rh
RH-ECP     3     28
f potential
  5
0    600.3243032             -0.0538958
1    157.6910176            -20.1316282
2     49.8841995           -105.3654121
2     15.5966895            -42.3274370
2      5.5099296             -3.6654043
s-f potential
  5
0     59.3442526              2.9753728
1     83.7426061             25.1230306
2     18.4530248            626.0926145
2     12.4194606           -812.2549385
2      8.8172913            467.3729340
p-f potential
  5
0     53.4309068              4.9537213
1     65.6671843             20.4871116
2     16.8369862            598.0120139
2     11.3042136           -718.4059028
2      8.0312444            382.8173151
d-f potential
  4
0     64.3993653              3.0279532
1     43.4625053             24.7526516
2     19.4020301            142.6844289
2      4.6879328             32.1406857
-Ag
AG-ECP     3     28
f potential
  5
0    568.7006237             -0.0587930
1    162.3579066            -20.1145146
2     51.1025755           -104.2733114
2     16.9205822            -40.4539787
2      6.1669596             -3.4420009
s-f potential
  5
0     76.0974658              2.9861527
1     15.3327359             35.1576460
2     18.7715345            450.1809906
2     13.3663294           -866.0248308
2      9.8236948            523.1110176
p-f potential
  5
0     56.3318043              4.9640671
1     69.0609098             21.5028219
2     19.2717998            546.0275453
2     12.5770654           -600.3822556
2      8.7956670            348.2949289
d-f potential
  5
0     53.4641078              3.0467486
1     40.1975457             23.3656705
2     11.9086073            777.2540117
2      9.7528183          -1238.8602423
2      8.1788997            608.0677121






