%nprocshared=20
%mem=8GB
#p opt freq=noraman wb97xd/genecp
scrf=(smd,solvent=dichloroethane)

Title Card Required

1 1
 O                  1.30777600    1.32755800   -1.19214900
 C                  2.20047400    1.78854400   -0.40759800
 O                  2.56282000    1.03819300    0.55214900
 C                 -2.24801100    0.58805200    0.43095800
 C                 -1.89423900    1.02941700   -0.83939400
 C                 -3.43953900   -0.09534200    0.65845400
 C                 -3.95643800    0.05457500   -1.56145300
 H                 -0.97111100    1.57288000   -1.01302100
 H                 -4.66905100   -0.17430100   -2.34874500
 Rh                 1.07649300   -0.40388500    0.04598300
 C                  0.06191900   -2.24685400    0.56885200
 H                 -0.78090500   -2.25561900    1.24774500
 C                  1.43005800   -2.31838000    0.95529400
 H                  1.80560600   -2.43470100    1.96174900
 C                  2.22240600   -2.17338200   -0.23282700
 H                  3.30291800   -2.14514200   -0.27999900
 C                 -0.00803800   -2.03694500   -0.83942900
 H                 -0.90942700   -1.90620200   -1.42153900
 C                  1.33396300   -2.00255300   -1.33729900
 H                  1.62675500   -1.81835800   -2.36241000
 C                  2.78456500    3.14769100   -0.58949700
 H                  2.39557000    3.61700400   -1.49453200
 H                  2.53720300    3.76117400    0.28364900
 H                  3.87420800    3.06614900   -0.64536300
 O                 -0.14516700    0.95392700    1.35285700
 O                 -1.84917200    0.93902700    2.66027300
 N                 -1.37253000    0.83402900    1.55542100
 H                 -3.69824100   -0.44221400    1.65502900
 N                 -4.28088500   -0.36969100   -0.33358000
 C                 -2.78788700    0.75394900   -1.86140100
 H                 -2.58924600    1.07850800   -2.87570200

-C -H -O -Si -N -F -Cl
6-31G(d,p)
****
-Br
LANL2DZ
D 1 1.0
0.428 1.0
****
-Rh
LANL2DZ
F 1 1.0
1.35 1.0
****
-Ag
LANL2DZ
F 1 1.0
1.611 1.0
****

-Br -Rh -Ag
LANL2DZ







